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Triphenylantimony and Pentaphenylantimony as the Starting Compounds for the Synthesis of Antimony(V) Phenyl Derivatives. Structure of Triphenylantimony, Bis(3,4-difluorobenzoato)triphenylantimony and Tetraphenylantimony Carbonate

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Abstract

The structure of triphenylantimony (I) was determined more accurately. Bis(3,4-difluorobenzoato)triphenylantimony Ph3Sb[OC(O)C6H3F2-3,4]2 (III) was obtained by the reaction of equimolar amounts of pentaphenylantimony solvate (Ph5Sb∙0.5PhH) (II) with 3,4-difluorobenzoic acid in benzene and characterized. The structure of the triclinic tetraphenylantimony carbonate (IV) was also determined more accurately. According to X-ray diffraction data (CCDC nos. 2117872 (I), 121388 (III), 2121833 (IV)), the crystals were characterized as follows. C36H30Sb2 (I): a = 10.941(11), b = 11.825(16), c = 13.747(13) Å; α = 102.57(5)°, β = 104.22(5)°, γ = 108.35(6)°; V = 1550(3) Å3; Z = 2. C32H21O4F4Sb (III): a = 12.652(5), b = 22.466(10), c = 11.561(5) Å; β = 120.027(15)°; V = 2845(2) Å3; Z = 4. C49H40O3Sb2 (IV): a = 10.093(4), b = 13.994(5), c = 15.665(6) Å; α = 73.917(15)°, β = 79.76(2)°, γ = 74.312(15)°; V = 2034.0(13) Å3; Z = 2. The antimony atoms in III have a distorted trigonal-bipyramidal coordination, with the oxygen atoms being located in axial positions (OSbO, 174.13(12)°; Sb–C, 2.101(3)–2.118(4) Å; Sb–O, 2.118(3) Å). The structural organization in the crystals of III and IV is formed by weak O···H–C intermolecular contacts (2.49 and 2.56 Å, respectively).

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Funding

This work was supported by the Russian Foundation for Basic Research (project no. 20-33-90099).

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  1. South Ural State University, Chelyabinsk, Russia

    A. N. Efremov & V. V. Sharutin

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  1. A. N. Efremov
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Translated by Z. Svitanko

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Efremov, A.N., Sharutin, V.V. Triphenylantimony and Pentaphenylantimony as the Starting Compounds for the Synthesis of Antimony(V) Phenyl Derivatives. Structure of Triphenylantimony, Bis(3,4-difluorobenzoato)triphenylantimony and Tetraphenylantimony Carbonate. Russ J Coord Chem 49, 56–62 (2023). https://doi.org/10.1134/S1070328422700324

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