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Rhenium(V) Tris(pyrazolyl)borate Complexes as Ligands in Square Planar Palladium and Platinum Complexes

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Abstract

The reactions of TpReO(SnC3H7)2 (Tp = tris(pyrazolyl)borate anion) with acetonitrile complexes PdCl2(MeCN)2 and PtI2(MeCN)2 in toluene solutions resulted in the formation of new heterometallic rhenium complexes TpReO(µ-SnC3H7)2MX2 (MX2 = PdCl2 (I), MX2 = PtI2 (II)). A similar complex TpReO(µ-SnC3H7)2PdI2 (III) was formed either on treatment of I with NaI in dichloromethane or in the reaction of TpReO(SnC3H7)2 with a suspension of PdI2 in toluene. Complexes I–III were characterized by IR and NMR spectroscopy and by X-ray diffraction (CCDC nos. 2172225–2172227).

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ACKNOWLEDGEMENTS

The studies were performed using equipment of the Center for Collective Use of Physical Investigation Methods of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

Funding

This study was supported by the Russian Science Foundation (grant no. 18-73-10206).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    I. V. Skabitskii, Yu. Ya. Il’ina & S. S. Shapovalov

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  1. I. V. Skabitskii
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  2. Yu. Ya. Il’ina
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  3. S. S. Shapovalov
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Correspondence to I. V. Skabitskii.

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The authors declare that they have no conflicts of interest.

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Translated by Z. Svitanko

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Skabitskii, I.V., Il’ina, Y.Y. & Shapovalov, S.S. Rhenium(V) Tris(pyrazolyl)borate Complexes as Ligands in Square Planar Palladium and Platinum Complexes. Russ J Coord Chem 49, 33–40 (2023). https://doi.org/10.1134/S1070328422700191

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  • DOI: https://doi.org/10.1134/S1070328422700191

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