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Structure and Thermal Characteristics of Bis(triethylammonium)-tetrakis(3,5-dinitro-2-pyridonato)cobalt(II)

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Abstract

The ionic compound [Co(OC5H2N(NO2)2)4]((C2H5)3NH)2 (I) was synthesized by the reaction of CoCl2·6H2O with 2-hydroxy-3,5-dinitropyridine in acetonitrile in the presence of triethylamine as a deprotonating agent. The structure of compound I was studied by X-ray diffraction (CCDC no. 2196071) and thermodynamic characteristics of I were determined.

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ACKNOWLEDGMENTS

This study was performed within the state assignment for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, in the field of fundamental research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    M. E. Nikiforova, D. B. Kayumova, I. P. Malkerova, A. S. Alikhanyan, M. A. Kiskin, A. A. Sidorov, A. V. Khoroshilov & I. L. Eremenko

  2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

    I. L. Dalinger, A. M. Starosotnikov & M. A. Bastrakov

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

    I. L. Eremenko

Authors
  1. M. E. Nikiforova
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  2. D. B. Kayumova
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  3. I. P. Malkerova
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  4. A. S. Alikhanyan
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  5. M. A. Kiskin
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  6. A. A. Sidorov
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  7. A. V. Khoroshilov
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  8. I. L. Dalinger
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  9. A. M. Starosotnikov
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  10. M. A. Bastrakov
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  11. I. L. Eremenko
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Corresponding author

Correspondence to M. E. Nikiforova.

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Translated by Z. Svitanko

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Nikiforova, M.E., Kayumova, D.B., Malkerova, I.P. et al. Structure and Thermal Characteristics of Bis(triethylammonium)-tetrakis(3,5-dinitro-2-pyridonato)cobalt(II). Russ J Coord Chem 49, 286–293 (2023). https://doi.org/10.1134/S1070328422600528

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  • DOI: https://doi.org/10.1134/S1070328422600528

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