Skip to main content
SpringerLink
Log in

Synthesis and Study of Complexes of 3,4-Bis(diphenylphosphinyl)-2,5-dimethylhexa-2,4-diene with Mn(II) Salts

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The coordination properties of 3,4-bis(diphenylphosphinyl)-2,5-dimethylhexa-2,4-diene (L2) were studied in relation to manganese(II) chloride and perchlorate complexes. Manganese(II) chloride forms 1 : 1 complex with bis-phosphine oxide L2, while the composition of the manganese(II) perchlorate complex is 2 : 1. The crystal structures of bis-phosphine oxide L2 complexes with manganese dichloride (CCDC no. 2165179) and manganese perchlorate (CCDC no. 2165180) were determined by X-ray diffraction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Harriman, A., Coord. Chem. Rev., 1979, vol. 28, p. 147.

    Article  CAS  Google Scholar 

  2. Tang, Y.-Y., Wang, Z.-H., Li, P.-F., et al., Inorg. Chem. Front., 2017, vol. 4, p. 154.

    Article  CAS  Google Scholar 

  3. Chen, J., Zhang, Q., Zheng, F.-K., et al., Dalton Trans., 2015, vol. 44, p. 3289.

    Article  CAS  PubMed  Google Scholar 

  4. Berezin, A.S., Samsonenko, D.G., Brel, V.K., and Artem’ev, A.V., Dalton Trans., 2018, vol. 47, p. 7306.

    Article  CAS  PubMed  Google Scholar 

  5. Bortoluzzi, M., Castro, J., Trave, E., et al., Inorg. Chem. Commun., 2018, vol. 90, p. 105.

    Article  CAS  Google Scholar 

  6. Davydova, M.P., Bauer, I.A., Brel, V.K., et al., Eur. J. Inorg. Chem., 2020, vol. 2020, p. 695.

    Article  CAS  Google Scholar 

  7. Qin, Y.Y., Tao, P., and Gao, L., Adv. Opt. Mater., 2019, vol. 7, р. 1801160.

  8. Berezin, A.S., Davydova, M.P., Bagryanskaya, I.Yu., et al., Inorg. Chem. Commun., 2019, vol. 107, р. 107473.

  9. Brel, V.K., Artyushin, O.I., Morgalyuk, V.P., et al., Russ. J. Coord. Chem., 2022, vol. 48, no. 4, p. 201. https://doi.org/10.1134/S1070328422040017

    Article  CAS  Google Scholar 

  10. Battye, T.G.G., Kontogiannis, L., Johnson, O., et al., Acta Crystallogr., Sect. D: Biol. Crystallogr., 2011, vol. 67, p. 271.

    Article  CAS  Google Scholar 

  11. Evans, P., Acta Crystallogr., Sect. D: Biol. Crystallogr., 2006, vol. 62, p. 72.

    Article  Google Scholar 

  12. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Adv., 2015, vol. 71, no. 1, p. 3.

    Article  Google Scholar 

  13. Sheldrick, G.M., Acta Crystallogr., Sect, C: Struct. Chem., 2015, vol. 71, no. 1, p. 3.

    Article  Google Scholar 

  14. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Cryst., 2009, vol. 42, p. 339.

    Article  CAS  Google Scholar 

  15. Jarvinen, M., J. Appl. Crystallogr., 1993, vol. 26, p. 525.

    Article  CAS  Google Scholar 

  16. Chen, F., Xia, Y., Lin, R., et al., Org. Lett., 2019, vol. 21, p. 579.

    Article  CAS  PubMed  Google Scholar 

Download references

ACKNOWLEDGMENTS

Elemental analysis and measurement of IR spectra were performed using equipment of the Center for Investigation of Molecular Structure, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, supported by the Ministry of Science and Higher Education of the Russian Federation.

Funding

This study was supported by the Russian Science Foundation (grant no. 20-13-00329).

Author information

Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

    V. P. Morgalyuk, O. I. Artyushin, A. V. Vologzhanina, B. V. Lokshin, A. G. Buyanovskaya, R. U. Takazova & V. K. Brel

  2. National Research Center “Kurchatov Institute”, Moscow, Russia

    P. V. Dorovatovskii

Authors
  1. V. P. Morgalyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. I. Artyushin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Vologzhanina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. V. Dorovatovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. B. V. Lokshin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. G. Buyanovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. R. U. Takazova
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. V. K. Brel
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. K. Brel.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by Z. Svitanko

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Morgalyuk, V.P., Artyushin, O.I., Vologzhanina, A.V. et al. Synthesis and Study of Complexes of 3,4-Bis(diphenylphosphinyl)-2,5-dimethylhexa-2,4-diene with Mn(II) Salts. Russ J Coord Chem 48, 754–759 (2022). https://doi.org/10.1134/S1070328422110069

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328422110069

Keywords:

Search

Navigation