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Specific Features of the Oxidative Addition of Triarylantimony to Dihydroxybenzoic Acids

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Abstract

Tris(2-methoxyphenyl)antimony and tris(3-fluorophenyl)antimony react with 2,3-dihydroxybenzoic and 3,4-dihydroxybenzoic acids in the presence of tert-butyl hydroperoxide to form carboxycatecholato-О,О'-triarylantimony. Under similar conditions, tris(4-fluorophenyl)antimony reacts with 2,3-dihydroxybenzoic acid to form tris(4-fluorophenyl)antimony dicarboxylate. Structural features of the reaction products are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2126358 (I), 2124252 (II·H2O·Et2O), 2121839 (III·0.5С6Н6), and 2131083 (IV·2.5С6Н6).

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Authors and Affiliations

  1. South Ural State University (National Research University), Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & V. V. Belov

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. V. V. Belov
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Correspondence to V. V. Sharutin.

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Translated by E. Yablonskaya

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Sharutin, V.V., Sharutina, O.K. & Belov, V.V. Specific Features of the Oxidative Addition of Triarylantimony to Dihydroxybenzoic Acids. Russ J Coord Chem 49, 167–175 (2023). https://doi.org/10.1134/S1070328422100220

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