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Complexes of Zinc, Nickel(II), and Cobalt(II) Cymantrenate Complexes with Pyrazole and 3,5-Dimethylpyrazole: Synthesis and Structural Features

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Abstract

The reaction of cymantrenates M[(OOС5CH4)Mn(CO)3]2(MeOH)4 (M = Zn, Co(II), Ni(II)) with pyrazole (HPz) results in replacement of labile methanol molecules by the heterocyclic ligand and gives mononuclear complexes Zn[(OOCC5H4)Mn(CO)3]2(HPz)2 (I), Ni[(OOCC5H4)Mn(CO)3]2(HPz)4 (II), and Co[(OOCC5H4)Mn(CO)3]2(HPz)4 (III). A similar reaction of cobalt cymantrenate with more basic and sterically bulky 3,5-dimethylpyrazole (HDmpz) gives the complex Co[(OOCC5H4)Mn(CO)3]2(HDmpz)2 (IV). Compounds I–IV were characterized by X-ray diffraction (CCDC nos. 2157671 (I), 2157672 (II), 2157669 (III), and 2157670 (IV)), IR spectroscopy, and elemental analysis.

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ACKNOWLEDGMENTS

X-ray diffraction and IR spectroscopic studies and elemental analysis were carried out using equipment of the Center for Collective Use of the Physical Investigation Methods of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, in the field of fundamental research.

Funding

This study was supported by the Ministry of Education and Science of the Russian Federation within the framework of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, in the field of fundamental research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    M. A. Uvarova & S. E. Nefedov

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  1. M. A. Uvarova
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  2. S. E. Nefedov
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Correspondence to M. A. Uvarova.

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Translated by Z. Svitanko

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Uvarova, M.A., Nefedov, S.E. Complexes of Zinc, Nickel(II), and Cobalt(II) Cymantrenate Complexes with Pyrazole and 3,5-Dimethylpyrazole: Synthesis and Structural Features. Russ J Coord Chem 48, 565–571 (2022). https://doi.org/10.1134/S107032842209007X

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  • DOI: https://doi.org/10.1134/S107032842209007X

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