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Layered trans-1,4-Cyclohexanedicarboxylates of Divalent Metals: Synthesis, Crystal Structures, and Thermal Properties

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Abstract

The reactions of magnesium nitrate with trans-1,4-cyclohexanedicarboxylic acid (H2Сhdc) in N,N-dimethylformamide (DMF) and N-methylpyrrolidone (NMP) as solvents afford new coordination polymers [Mg3(DMF)4(Chdc)3] (I), [Mg3(DMF)2(NMP)2(Сhdc)3] (II), and [Mg3(NMP)4(Сhdc)3] (III). Coordination polymer [Ca3(NMP)4(Chdc)3] (IV) is synthesized from calcium acetate and H2Chdc in NMP. The reaction of cadmium nitrate with H2Сhdc and urotropine (Ur) in DMF gives coordination polymer [Cd(Ur)(DMF)(Chdc)] (V). The structures of the synthesized compounds are determined by single-crystal X-ray diffraction (XRD) (CIF files CCDC nos. 2120662 (I), 2120666 (II), 2120664 (III), 2120663 (IV), and 2120665 (V)). The coordination polymers of alkaline-earth metals (I–IV) are based on trinuclear carboxylate blocks {M3(OOC)6} linked by the dicarboxylate linkers into trigonal layers. The cadmium compound (V) is built of the mononuclear fragments {Cd(NUr)2(DMF)(OOC)2} linked by bridging trans-1,4-cyclohexanedicarboxylates and urotropine molecules into polymer layers. Compounds I–III are characterized by IR spectroscopy, elemental analysis, and thermogravimetric analysis.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation, project no. 121031700321-3.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Demakov & V. P. Fedin

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  1. P. A. Demakov
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  2. V. P. Fedin
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Correspondence to V. P. Fedin.

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Translated by E. Yablonskaya

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Demakov, P.A., Fedin, V.P. Layered trans-1,4-Cyclohexanedicarboxylates of Divalent Metals: Synthesis, Crystal Structures, and Thermal Properties. Russ J Coord Chem 48, 270–277 (2022). https://doi.org/10.1134/S1070328422050049

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