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Copper(II) and Cobalt(II) Carboxylates Containing the 1,3,4-Oxadiazole Fragment: Structures and Properties

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Abstract

Complexes [Сu2L4(MeOH)2] (I) and [СoL2] (II) are synthesized by the reactions of copper(II) and cobalt(II) acetates with 3-[5-p-tolyl)-1,3,4-oxadiazol-2-yl]acrylic acid (HL). The crystal structure of complex I is determined by X-ray diffraction (XRD) (CIF file CCDC no. 2052347). The crystals are monoclinic, space group C2/c, a = 26.056(4), b = 19.677(3), c = 13.998(2) Å, β = 91.571(3)°, V = 7175(2) Å3, ρcalc = 1.026 g/cm3, Z = 4. In a molecule of complex I, the pair of centrosymmetric copper atoms is bound by four bridging carboxyl groups. The intramolecular Cu…Cu distance is 2.654(2) Å. The coordination polyhedron CuO5 is a distorted square pyramid. The magnetic interactions between the copper(II) ions in complex I are shown to be antiferromagnetic (2J = –185 cm–1). In the case of complex II, the application of an external magnetic field decreases the magnetic relaxation rate. The Raman mechanism and direct mechanism are the most probable route for magnetization relaxation. Unlike the copper(II) complex, complex II is probably mononuclear in both the solution and solid phase.

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ACKNOWLEDGMENTS

The XRD, magnetic, and EPR studies were carried out using the equipment of the Center for Collective Use “Physical Methods of Investigation” at the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) supported by the state assignment of the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) in the area of basic research.

Funding

The NMR studies were performed under the support of the Russian Science Foundation (project no. 20-73-00194) using the equipment of the Center for Molecular Composition Studies at the Nesmeyanov Institute of Organoelement Compounds (Russian Academy of Sciences).

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Correspondence to L. D. Popov, A. A. Pavlov or V. V. Minin.

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Translated by E. Yablonskaya

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Popov, L.D., Borodkin, S.A., Kiskin, M.A. et al. Copper(II) and Cobalt(II) Carboxylates Containing the 1,3,4-Oxadiazole Fragment: Structures and Properties. Russ J Coord Chem 48, 75–83 (2022). https://doi.org/10.1134/S1070328422020051

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