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Lanthanide Iodide Nitride Sulfide Clusters

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Abstract

The reaction of [(NdI)3N2] (I) with Cp3Er in the presence of sulfur in THF gave CpNdI2(THF), NdI(S2N2)(THF), and an unidentified erbium compound. A similar reaction of [(DyI)3N2] yielded CpDyI2(THF) and ErI(S2N2)(THF). When I reacted with ErCl3, the clusters [Nd2ErClI4-(S2)(S2N2)(THF)7] and [Nd2ErCl2I3(S2)(S2N2)(THF)7] were formed in 33–34% yield. From the mixture of reaction products of [(DyI)3N2] with sulfur and NdI3, only [Nd2DyI5(S2)(S2N2)(THF)7] was isolated in a minor yield and identified. Europium diiodide EuI2 almost did not react with complex I and sulfur under the chosen conditions. The starting EuI2 (50%) and previously characterized cluster [Nd3I5(S2)(S2N2)(THF)9] were isolated from the reaction mixture.

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ACKNOWLEGMENTS

The study was carried out using the equipment of the Center for Collective Use “Analytical Center of the Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences” supported by the grant “Provision of Development of the Material and Technical Infrastructure of Centers for Collective Use of Research Equipment” (unique identifier RF-2296.61321X0017, agreement no. 075-15-2021-670).

Funding

This study was supported by the Russian Foundation for Basic Research (project no. 18-43-520002).

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    A. A. Fagin, O. V. Kuznetsova, R. V. Rumyantsev, E. V. Baranov, G. K. Fukin & M. N. Bochkarev

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  1. A. A. Fagin
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  2. O. V. Kuznetsova
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  3. R. V. Rumyantsev
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  4. E. V. Baranov
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  5. G. K. Fukin
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  6. M. N. Bochkarev
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Corresponding authors

Correspondence to O. V. Kuznetsova or M. N. Bochkarev.

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The authors declare that they have no conflicts of interest.

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Translated by Z. Svitanko

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Fagin, A.A., Kuznetsova, O.V., Rumyantsev, R.V. et al. Lanthanide Iodide Nitride Sulfide Clusters. Russ J Coord Chem 48, 146–152 (2022). https://doi.org/10.1134/S1070328422020026

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  • DOI: https://doi.org/10.1134/S1070328422020026

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