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Syntheses, Structures, Luminescence Properties of Two Coordination Polymers Constructed by a Semirigid Aromatic Multicarboxylite Ligand

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Abstract

Two new coordination polymers, namely {[Zn3(bcpmba)2(Py)6]·2H2O}n (I) and {[Cd(Hbcpmba)]· H2O}n (II) (H3bcpmba = 3,5-bi(4-carboxy-phenylene-methylene-oxy)-benzoic acid, Py = pyridine) have been synthesized under hydrothermal conditions. All the compounds are characterized using powder X-ray diffraction (CIF file. CCDC nos. 2051308 (I) and 2051312 (II)), IR spectra, thermal st-ability analysis, and elemental analyses. Compounds I and II are all 2D porous CPs. The effects of the bcpmba3− anions, and the N-donor ligands on the structures of the coordination polymers have been discussed. Moreover, their photoluminescence properties and thermal stability of them have been investigated.

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Funding

This work is supported by the start-up foundation of Sichuan University of Science and Engineering (no. 2015RC29).

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Authors and Affiliations

  1. College of Chemistry and Environmental Engineering, Sichuan University of Science and Engineering, 643000, Zigong, P.R. China

    Y. C. Sun, Q. Q. Wei & Q. X. Wang

  2. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physical-Inorganic Chemistry, 710069, Xi’an, P.R. China

    J. S. Zhao

Authors
  1. Y. C. Sun
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  2. Q. Q. Wei
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  4. J. S. Zhao
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Correspondence to Y. C. Sun.

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Sun, Y.C., Wei, Q.Q., Wang, Q.X. et al. Syntheses, Structures, Luminescence Properties of Two Coordination Polymers Constructed by a Semirigid Aromatic Multicarboxylite Ligand. Russ J Coord Chem 48, 60–68 (2022). https://doi.org/10.1134/S1070328422010067

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  • DOI: https://doi.org/10.1134/S1070328422010067

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