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Electron Density Distribution in the Crystal of the Biocompatible Metal–Organic Framework

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Abstract

The earlier described organic coordination polymer [Zn3(HCit)2(H2O)2]n (HCit is citric acid) (I) formed completely by the biocompatible components is synthesized under hydrothermal conditions. The selection of the hydrothermal synthesis conditions makes it possible to obtain the polymer as high-quality single crystals and perform a detailed analysis of the electron density distribution function recovered using the data of a high-resolution X-ray diffraction experiment. This study is the second example of such investigations for the biocompatible metal−organic framework.

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ACKNOWLEDGMENTS

The elemental analysis of the synthesized product was performed under the support of the Ministry of Science and Higher Education of the Russian Federation using the equipment of the Center for Molecular Composition Studies at the Nesmeyanov Institute of Organoelement Compounds (Russian Academy of Sciences).

Funding

This work was supported by the Russian Science Foundation, project no. 20-73-10200.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    A. A. Ishchenko, A. M. Pak & Yu. V. Nelyubina

  2. Moscow Institute of Physics and Technology (National Research University), Dolgoprudnyi, Moscow oblast, Russia

    A. A. Ishchenko & Yu. V. Nelyubina

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  1. A. A. Ishchenko
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  2. A. M. Pak
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  3. Yu. V. Nelyubina
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Correspondence to Yu. V. Nelyubina.

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Translated by E. Yablonskaya

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Ishchenko, A.A., Pak, A.M. & Nelyubina, Y.V. Electron Density Distribution in the Crystal of the Biocompatible Metal–Organic Framework. Russ J Coord Chem 48, 16–25 (2022). https://doi.org/10.1134/S107032842201002X

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  • DOI: https://doi.org/10.1134/S107032842201002X

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