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A New Metal-Organic Framework: Product of Solvothermal Synthesis in 3D-Printed Autoclaves

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Abstract

A new metal-organic framework {Zn4(BDC)3(OAc)2(DMF)4} (BDC = terephthalate anion) was synthesized under solvothermal conditions in a 3D-printed polypropylene autoclave. The product was isolated in a pure state and characterized by elemental analysis and X-ray diffraction (CIF file CCDC no. 2025811). The formation of this product, instead of the expected {Zn4O(BDC)3} (MOF-5), was probably due to a change in the conditions of solvothermal synthesis caused by disruption of the integrity of the polypropylene autoclave. This is a drawback of this method of screening of metal-organic frameworks, which, however, in some cases givs rise to new representatives of this class of crystalline materials.

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ACKNOWLEDGMENTS

The composition and structure of the product were studied using research equipment of the Center for Studies of Molecular Structure of the Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, supported by the Ministry of Science and Higher Education of the Russian Federation.

Funding

This study was supported by the Russian Foundation for Basic Research (grant no. 19-29-08032). The design and manufacture of the automated unit for dispensing of reactants was supported by the Russian Foundation for Basic Research (grant no. 19-33-90260).

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

    G. L. Denisov, P. V. Primakov & Yu. V. Nelyubina

  2. Moscow State University, Moscow, Russia

    P. V. Primakov

Authors
  1. G. L. Denisov
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  2. P. V. Primakov
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  3. Yu. V. Nelyubina
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Correspondence to Yu. V. Nelyubina.

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Translated by Z. Svitanko

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Denisov, G.L., Primakov, P.V. & Nelyubina, Y.V. A New Metal-Organic Framework: Product of Solvothermal Synthesis in 3D-Printed Autoclaves. Russ J Coord Chem 47, 253–260 (2021). https://doi.org/10.1134/S1070328421040011

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  • DOI: https://doi.org/10.1134/S1070328421040011

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