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Specific Features of EPR Spectroscopy of Organotin Compounds with Paramagnetic Ligands of the o-Iminobenzosemiquinone Type

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Abstract

New paramagnetic tin(IV) derivatives containing the radical-anion of 2,4,6,8-tetra-tert-butylphenoxazin-1-one redox-active ligand (phenox-imQ) are synthesized and studied by EPR spectroscopy. Complexes I–V are paramagnetic in the crystalline state and in solution. The geometry of the obtained paramagnetic species and spin density distribution in them are studied by the Density functional theory. Diamagnetic complex VI is synthesized from the phenox-imQ dianion, and its one-electron oxidation is studied. The molecular structure of complex VI · ТHF is determined by X-ray diffraction analysis (CIF file CCDC no. 2000962 (VI · ТHF)).

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ACKNOWLEDGMENTS

The studies were carried out in terms of state assignment using the equipment of the Analytical Center for Collective Use at the Razuvaev Institute of Organometallic Chemistry (Russian Academy of Sciences)

Funding

This work was supported by the federal target program “Research and Design on Priority Directions of Development of Scientific Technological Complex of Russia for 2014–2020” (project no. RFMEFI62120X0040).

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia

    M. G. Chegerev

  2. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603600, Nizhny Novgorod, Russia

    K. V. Arsenyeva, A. V. Cherkasov & A. V. Piskunov

Authors
  1. M. G. Chegerev
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  2. K. V. Arsenyeva
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  3. A. V. Cherkasov
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  4. A. V. Piskunov
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Correspondence to A. V. Piskunov.

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Translated by E. Yablonskaya

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Chegerev, M.G., Arsenyeva, K.V., Cherkasov, A.V. et al. Specific Features of EPR Spectroscopy of Organotin Compounds with Paramagnetic Ligands of the o-Iminobenzosemiquinone Type. Russ J Coord Chem 46, 746–755 (2020). https://doi.org/10.1134/S1070328420110019

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