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Synthesis and Structure of New Polymeric Lithium Pivalates

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Abstract

Data on the synthesis and study of the crystal structure of [Li10(Piv)10(MeCN)2]n (I) and [Li6(Piv)6(MeCN)2]n (II) are presented. According to X-ray diffraction data (CIF files CCDC nos. 1957855 (I); 1955569 (II)), compounds I and II are 1D polymers composed of deca- and hexanuclear fragments, respectively, in which the lithium atoms are linked to one another by μ3- and μ4-bridging pivalate anions.

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ACKNOWLEDGMENTS

X-ray diffraction, IR spectroscopy, and elemental analysis were performed using Shared Experimental Facilities supported by IGIC RAS State Assignment .

Funding

This work was supported by the Russian Foundation for Basic Research (project no. 18-29-04043).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    E. N. Zorina-Tikhonova, D. S. Yambulatov, M. A. Kiskin, E. S. Bazhina, S. A. Nikolaevskii, N. V. Gogoleva, I. A. Lutsenko, A. A. Sidorov & I. L. Eremenko

Authors
  1. E. N. Zorina-Tikhonova
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  2. D. S. Yambulatov
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  3. M. A. Kiskin
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  4. E. S. Bazhina
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  5. S. A. Nikolaevskii
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  6. N. V. Gogoleva
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  7. I. A. Lutsenko
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  8. A. A. Sidorov
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  9. I. L. Eremenko
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Corresponding author

Correspondence to S. A. Nikolaevskii.

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The authors declare that they have no conflicts of interest.

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Translated by Z. Svitanko

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Zorina-Tikhonova, E.N., Yambulatov, D.S., Kiskin, M.A. et al. Synthesis and Structure of New Polymeric Lithium Pivalates . Russ J Coord Chem 46, 75–80 (2020). https://doi.org/10.1134/S1070328420020104

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  • DOI: https://doi.org/10.1134/S1070328420020104

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