Skip to main content
SpringerLink
Log in

3a,6a-Diaza-1,4-Diphosphapentalene Complexes with Lewis Acids InI3 and SbCl3

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

3a,6a-Diaza-1,4-diphosphapentalene (DDP) with indium triiodide forms the [In(DDP)I3] complex (I) with the ratio In : DDP = 1 : 1. The DDP ligand reacts with antimony(III) chloride to form a coordination polymer, the treatment of which with pyridine in the presence of pyridine hydrochloride affords the [PyH]+[Sb(DDP)Cl4)]– complex (II) (CIF files CCDC nos. 1937822 (I) and 1937823 (II)). The metal is coordinated to the phosphorus atom at an angle to the plane of the heteropentalene cycle (101.9(1)° and 106.0(1)° for In and Sb, respectively). This indicates that the coordination occurs due to electrons of the heteroaromatic π system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Kornev, A.N., Sushev, V.V., Panova, Y.S., et al., Inorg. Chem., 2014, vol. 53, p. 3243.

    Article  CAS  Google Scholar 

  2. Bansal, R.K., Phosphorous Heterocycles I: Top. Heterocycl. Chem., Berlin-Heidelberg: Springer, 2009, vol. 20, p. 1.

    Book  Google Scholar 

  3. Kornev, A.N., Sushev, V.V., Kireeva, V.V., et al., Dokl. Chem., 2015, vol. 462, p. 145.

    Article  CAS  Google Scholar 

  4. Kornev, A.N., Galperin, V.E., Sushev, V.V., et al., Eur. J. Inorg. Chem., 2016, vol. 22, p. 3629.

    Article  Google Scholar 

  5. Kornev, A.N., Galperin, V.E., Sushev, V.V., et al., Russ. Chem. Bull., 2016, vol. 65, no. 11, p. 2658.

    Article  CAS  Google Scholar 

  6. Heinicke, J.W., Ghalib, M., Schulzke, C., et al., Phosphorus Sulfur Silicon Relat. Elem., 2015, vol. 190, nos. 5–6, p. 806.

    Article  CAS  Google Scholar 

  7. Ghalib, M., Niaz, B., Jones, P.G., and Heinicke, J.W., Heteroatom. Chem., 2013, vol. 24, no. 6, p. 452.

    Article  CAS  Google Scholar 

  8. Data Collection. Reduction and Correction Program, CrysAlisPro—Software Package. Agilent Technologies, 2014.

  9. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Adv., 2015, vol. 71, p. 3.

    Article  Google Scholar 

  10. Sheldrick G.M., SHELXTL. Version 6.14. Structure Determination Software Suite, Madison: Bruker AXS, 2003.

    Google Scholar 

  11. Sheldrick, G.M., Acta Crystallogr., Sect. C: Struct. Chem., 2015, vol. 71, p. 3.

    Article  Google Scholar 

  12. SCALE3 ABSPACK. Empirical Absorption Correction. CrysAlisPro—Software Package, Agilent Technologies, 2014.

  13. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., et al., J. Appl. Crystallogr., 2009, vol. 42, p. 339.

    Article  CAS  Google Scholar 

  14. Batsanov, S.S., Russ. J. Inorg. Chem., 1991, vol. 36, no. 12, p. 1694.

    Google Scholar 

  15. Brown, M.A., Tuck, D.G., and Wells, E.J., Can. J. Chem., 1996, vol. 74, p. 1535.

    Article  CAS  Google Scholar 

  16. Chitnis, S.S., Burford, N., McDonald, R., et al., Inorg. Chem., 2014, vol. 53, p. 5359.

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported by the Russian Science Foundation, project no. 19-13-00400.

Author information

Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137, Nizhny Novgorod, Russia

    A. N. Kornev, Yu. S. Panova, V. V. Sushev, V. E. Galperin, A. V. Sheyanova, G. K. Fukin, E. V. Baranov & G. A. Abakumov

Authors
  1. A. N. Kornev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. S. Panova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. V. Sushev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. E. Galperin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. V. Sheyanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. G. K. Fukin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. E. V. Baranov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. G. A. Abakumov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. N. Kornev.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by E. Yablonskaya

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kornev, A.N., Panova, Y.S., Sushev, V.V. et al. 3a,6a-Diaza-1,4-Diphosphapentalene Complexes with Lewis Acids InI3 and SbCl3. Russ J Coord Chem 46, 98–104 (2020). https://doi.org/10.1134/S1070328420020050

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328420020050

Keywords:

Search

Navigation