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Coordination Polymers Based on Oxovanadium(IV) Butylmalonate Fragments and Potassium, Magnesium, and Cadmium Cations

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Abstract

The data on the synthesis and study of the crystal structure of compounds {[K2Mg2(VO)3(Bumal)6(H2O)15] · 2H2O}n (I) and {[Cd(VO)(Bumal)2(H2O)5] · H2O}n (II) are presented. According to X-ray diffraction, these compounds are formed by the anionic fragments [VO(Bumal)2(H2O)]2– with oxovanadium(IV) and two butylmalonate anions (H2Bumal is C5H10(COOH)2) coordinated via the chelate mode. In the crystals of compound I (CIF file CCDC no. 1911220), the [VO(Bumal)2(H2O)]2– anionic fragments are bound to each other by the K+ and Mg2+ cations into the 2D polymeic structure. In compound II (CIF file CCDC no. 1033008), these fragments are bound by the Cd2+ cations to form the 1D coordination polymer.

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ACKNOWLEDGMENTS

Elemental CHNS analyses, IR spectroscopy, and X-ray structure analysis were carried out using Shared Experimental Facilities of the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) supported by IGIC RAS State Assignment.

Funding

This work was supported by the Russian Science Foundation, project no. 19-73-10181.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    E. S. Bazhina, G. G. Aleksandrov, M. A. Kiskin, A. A. Sidorov & I. L. Eremenko

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  1. E. S. Bazhina
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  2. G. G. Aleksandrov
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  3. M. A. Kiskin
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  4. A. A. Sidorov
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  5. I. L. Eremenko
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Correspondence to E. S. Bazhina.

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Translated by E. Yablonskaya

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Bazhina, E.S., Aleksandrov, G.G., Kiskin, M.A. et al. Coordination Polymers Based on Oxovanadium(IV) Butylmalonate Fragments and Potassium, Magnesium, and Cadmium Cations. Russ J Coord Chem 46, 89–97 (2020). https://doi.org/10.1134/S1070328420020025

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  • DOI: https://doi.org/10.1134/S1070328420020025

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