Skip to main content
SpringerLink
Log in

Synthesis, Characterization, Crystal Structures and Antimicrobial Activity of Oxidovanadium(V) Complexes with Mixed Ligands

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Two new oxidovanadium(V) complexes, [VOLL1] (I) and [VOLL2] (II), where L is the dianionic form of the hydrazone ligand 2-cyano-N'-(2-hydroxy-3-methoxybenzylidene)acetohydrazide (H2L), L1 and L2 are the deprotonated form of 2-hydroxybenzohydroxamate (HL1) and 3-hydroxy-2-methyl-4H-pyran-4-one (HL2), respectively, have been prepared and characterized by elemental analyses, IR, UV-Vis, 1H NMR and single crystal X-ray crystallographic determination (СIF files CCDC nos. 1880992 (I) and 1880993 (II)). The V atoms in the complexes are in octahedral coordination with the hydrazone ligand coordinates to the metal atoms through the phenolate O, imino N and enolate O atoms, and with 2-hydroxybenzohydroxamate and 3-hydroxy-2-methyl-4H-pyran-4-one through the carbonyl and hydroxyl O atoms. The effect of the compounds on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans was studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Burlov, A.S., Vlasenko, V.G., Koshchienko, Y.V., et al., Polyhedron, 2018, vol. 154, p. 65.

    Article  CAS  Google Scholar 

  2. Salman, Y., Barlas, F.B., Yavuz, M., et al., Inorg. Chim. Acta, 2018, vol. 483, p. 98.

    Article  CAS  Google Scholar 

  3. Muche, S., Harms, K., Biernasiuk, A., et al., Polyhedron, 2018, vol. 151, p. 465.

    Article  CAS  Google Scholar 

  4. Valentova, J., Varenyi, S., Herich, P., et al., Inorg. Chim. Acta, 2018, vol. 480, p. 16.

    Article  CAS  Google Scholar 

  5. Soliman, S.M., El-Faham, A., Elsilk, S.E., et al., Inorg. Chim. Acta, 2018, vol. 479, p. 275.

    Article  CAS  Google Scholar 

  6. Nithya, P., Rajamanikandan, R., Simpson, J., et al., Polyhedron, 2018, vol. 145, p. 200.

    Article  CAS  Google Scholar 

  7. Jana, K., Das, S., Maity, T., et al., J. Coord. Chem., 2018, vol. 71, no. 10, p. 1497.

    Article  CAS  Google Scholar 

  8. Qian, H.Y., Russ. J. Coord. Chem., 2018, vol. 44, no. 1, p. 32.

    Article  CAS  Google Scholar 

  9. Ribeiro, N., Roy, S., Butenko, N., et al., J. Inorg. Biochem., 2017, vol. 174, p. 63.

    Article  CAS  Google Scholar 

  10. Silver, M.A., Cary, S.K., Stritzinger, J.T., et al., Inorg. Chem., 2016, vol. 55, no. 11, p. 5092.

    Article  CAS  Google Scholar 

  11. Orlowska, E., Roller, A., Wiesinger, H., et al., RSC Adv., 2016, vol. 6, no. 46, p. 40238.

    Article  CAS  Google Scholar 

  12. Vishwakarma, P.K., Mir, J.M., and Maurya, R.C., J. Chem. Sci., 2016, vol. 128, no. 4, p. 511.

    Article  CAS  Google Scholar 

  13. Failes, T.W., Hall, M.D., and Hambley, T.W., Dalton Trans., 2003, no. 8, p. 1596.

  14. Sheng, G.H., Huo, Y., Ye, Y.T., et al., Russ. J. Coord Chem., 2014, vol. 40, no. 9, p. 664. https://doi.org/10.1134/S1070328414090085

    Article  CAS  Google Scholar 

  15. Sharma, N., Kumari, M., Kumar, V., et al., J. Coord. Chem., 2010, vol. 63, no. 11, p. 1940.

    Article  CAS  Google Scholar 

  16. Soujanya, M., Rajitha, G., Umamaheswari, A., et al., Lett. Drug Des. Discov., 2018, vol. 15, no. 8, p. 875.

    Article  CAS  Google Scholar 

  17. Kumar, S.S., Biju, S., and Sadasivan, V., J. Mol. Struct., 2018, vol. 1156, p. 201.

    Article  CAS  Google Scholar 

  18. SMART and SAINT. Area Detector Control and Integration Software, Madison: Bruker Analytical X-ray Instruments Inc., 1997.

  19. Sheldrick, G.M., SADABS, Program for Empirical Absorption Correction of Area Detector Data, Göttingen: Univ. of Göttingen, 1997.

    Google Scholar 

  20. North, A.C.T., Phillips, D.C., and Mathews, F.S., Acta Crystallogr., Sect. A, 1968, vol. 24, no. 3, p. 351.

    Article  Google Scholar 

  21. Sheldrick, G.M., SHELXL-97, Program for the Refinement of Crystal Structures, Göttingen: Univ. of Göttingen, 1997.

    Google Scholar 

  22. Sarkar, A. and Pal, S., Polyhedron, 2006, vol. 25, no. 7, p. 1689.

    Article  CAS  Google Scholar 

  23. Sarkar, A. and Pal, S., Inorg. Chim. Acta, 2008, vol. 361, no. 8, p. 2296.

    Article  CAS  Google Scholar 

  24. Asgedom, G., Sreedhara, A., Kivikoski, J., et al., Dalton Trans., 1996, no. 1, p. 93.

  25. Guo, S.H., Sun, N., Ding, Y.W., et al., Z. Anorg. Allg. Chem., 2018, vol. 644, no. 19, p. 1172.

    Article  CAS  Google Scholar 

  26. Li, L., Lv, K.-W., Li, Y.-T., et al., Chin. J. Inorg. Chem., 2017, vol. 33, no. 5, p. 905.

    CAS  Google Scholar 

  27. Rosu, T., Negoiu, M., and Pasculescu, S., Eur. J. Med. Chem., 2010, vol. 45, no. 2, p. 774.

    Article  CAS  Google Scholar 

  28. Searl, J.W., Smith, R.C., and Wyard, S.J., Proc. Phys. Soc. London, 1961, vol. 78, no. 505, p. 1174.

    Article  CAS  Google Scholar 

Download references

Funding

This research was supported by the Top-class foundation of Pingdingshan University (nos. PXY-BSQD-2018006 and PXY-PYJJ-2018002).

Author information

Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Pingdingshan University, 467000, Pingdingshan, Henan, P.R. China

    X. Q. Luo, Y. J. Han & L. W. Xue

Authors
  1. X. Q. Luo
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Y. J. Han
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. W. Xue
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. W. Xue.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Luo, X.Q., Han, Y.J. & Xue, L.W. Synthesis, Characterization, Crystal Structures and Antimicrobial Activity of Oxidovanadium(V) Complexes with Mixed Ligands. Russ J Coord Chem 46, 58–63 (2020). https://doi.org/10.1134/S1070328420010054

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328420010054

Keywords:

Search

Navigation