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Boron Cluster Anions [B10X10]2– (X = H, Cl) in Manganese(II) Complexation with 2,2'-Bipyridyl

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Abstract

The complexation of manganese(II) with 2,2'-bipyridyl in the presence of the [B10H10]2– and [B10Cl10]2– boron cluster anions has been studied in acetonitrile. The effect of the ratio of reagents on the composition and structure of final complexes has been shown. Mono- and binuclear manganese(II) complexes [(Mn(Bipy)3]2+ and [Mn2(Bipy)4Cl2]2+ have been synthesized with the boron cluster anions as counterions. The X-ray diffraction studies have been performed for complexes [Mn(Bipy)3][B10Cl (I)10] (I), [Mn(Bipy)3][B10Cl10]0.5[B10Cl9H]0.5 · CH3CN (III· CH3CN), and [Mn2(Bipy)4(µ-Cl)2][B10Cl10] · 2CH3CN (IV ⋅ 2CH3CN) (CIF files CCDC nos. 1868278 (I), 1868279 (III · CH3CN), 1868280 (IV · 2CH3CN)). Thermal properties of complex I have been studied.

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ACKNOWLEDGMENTS

This work was supported by the Council for Grants of the President of the Russian Federation for State Support of Leading Scientific Schools (grant NSh-2845.2018.3, chemistry of the [B10Cl10]2– anion) and the Russian Science Foundation (grant 14-13-01115, chemistry of the [B10H10]2– anion).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    V. V. Avdeeva, E. A. Malinina, K. Yu. Zhizhin & N. T. Kuznetsov

  2. Nesmeyanov Institute of Organoelement Compounds, 119991, Moscow, Russia

    A. V. Vologzhanina

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  1. V. V. Avdeeva
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  2. A. V. Vologzhanina
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  3. E. A. Malinina
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  4. K. Yu. Zhizhin
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Correspondence to V. V. Avdeeva.

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Dedicated to the 90th birthday of Academician I.I. Moiseev

Translated by V. Avdeeva

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Avdeeva, V.V., Vologzhanina, A.V., Malinina, E.A. et al. Boron Cluster Anions [B10X10]2– (X = H, Cl) in Manganese(II) Complexation with 2,2'-Bipyridyl. Russ J Coord Chem 45, 295–300 (2019). https://doi.org/10.1134/S1070328419040018

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