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Russian Journal of Coordination Chemistry

, Volume 45, Issue 3, pp 208–214 | Cite as

Crystal Structure of Mono- and Trinuclear Ni(II) Complexes with Bis-Azomethine Based on 2-Amino-3-Formylpyridine

  • Yu. P. TupolovaEmail author
  • S. I. Levchenkov
  • L. D. Popov
  • S. V. Posokhova
  • A. A. Aleksandrov
Article
  • 25 Downloads

Abstract

The structure of a new mononuclear nickel(II) complex with bis-azomethine [Ni(H2L)]+ · CH3COO · H2O, resulting from condensation of 1,3-diaminopropan-2-ol with 2-amino-3-formylpyridine (H3L), was studied by X-ray diffraction (CIF files CCDC nos. 1562927, 1562928). Apart from the mononuclear complex, the reaction gave a minor amount of the trinuclear metal chelate [Ni3L'(H2O)2]+ · (CH3COO) · CH3OH · H2O, where L' is N5O2-donor ligand containing two 3-(((2-aminopyridin-2-yl)methylene)amino)-1-aminopropan-2-ol moieties linked by a 2-aminopyridine-3-methylene group.

Keywords:

bis-azomethines Ni(II) complexes X-ray diffraction 

Notes

REFERENCES

  1. 1.
    Lukov, V.V., Shcherbakov, I.N., Levchenkov, S.I., et al., Russ. J. Coord. Chem., 2017, vol. 43, no. 1, p. 1134.CrossRefGoogle Scholar
  2. 2.
    Hay, P.J., Thibeault, J.C., and Hoffmann, R., J. Am. Chem. Soc., 1975, p. 4884.Google Scholar
  3. 3.
    Nishida, Y. and Kida, S., Inorg. Chem., 1988, vol. 27, no. 3, p. 447.CrossRefGoogle Scholar
  4. 4.
    Elmali, A., Zeyrek, C.T., and Elerman, Y., J. Mol. Struct., 2004, vol. 693, nos. 1−3, p. 225.CrossRefGoogle Scholar
  5. 5.
    Yamaguchi, K., Takahara, Y., Fueno, T., and Houk, K.N., Theor. Chim. Acta, 1988, vol. 73, no. 5, p. 337.CrossRefGoogle Scholar
  6. 6.
    Tupolova, Y.P., Kogan, V.A., Lukov, V.V., et al., Transition Met. Chem., 2007, no. 32, p. 656.Google Scholar
  7. 7.
    Chou, Y.-C., Huang, S.-F., Koner, R., et al., Inorg. Chem., 2004, vol. 43, no. 9, p. 2759.CrossRefGoogle Scholar
  8. 8.
    Kogan, V.A., Lukov, V.V., Novotortsev, V.M., et al., Izv. Akad. Nauk. Ser. Khim., 2005, vol. 4. no. 3, p. 592.Google Scholar
  9. 9.
    Lee, C.-J., Cheng, S.-C., Lin, H.-H., and Wei, H.-H., Inorg. Chem. Commun., 2005, vol. 8, no. 3, p. 235.CrossRefGoogle Scholar
  10. 10.
    Popov, L.D., Levchenkov, S.I., and Shcher-bakov, I.N., et al., Inorg. Chem. Commun., 2012, vol. 17, p. 1.CrossRefGoogle Scholar
  11. 11.
    Shcherbakov, I.N., Levchenkov, S.I., Tupolova, Y.P., et al., Eur. J. Inorg. Chem., 2013, vol. 2013, no. 28, p. 5033.Google Scholar
  12. 12.
    Levchenkov, S.I., Shcherbakov, I.N., Popov, L.D., et al., Russ. J. Coord. Chem., 2014, vol. 40, no. 8, p. 1134.Google Scholar
  13. 13.
    Popov, L.D., Tupolova, Y.P., Lukov, V.V., et al., Inorg. Chim. Acta, 2009, vol. 362, p. 1673.CrossRefGoogle Scholar
  14. 14.
    Shcherbakov, I.N., Levchenkov, S.I., Popov, L.D., et al., Russ. J. Coord. Chem., 2015, vol. 41, no. 2, p. 69.CrossRefGoogle Scholar
  15. 15.
    Swamy, B., Swamy, J., and Ramanuja, J., Orient. J. Chem., 1990, vol. 6, p. 95.Google Scholar
  16. 16.
    Dasharatham, D., J. Chem. Pharm. Sci., 2011, vol. 4, p. 66.Google Scholar
  17. 17.
    Fernando, M.R. and Ávalos, M., Babianol, R., and Cintas, P., Eur. J. Org. Chem., 2010, vol. 32, p. 6224.CrossRefGoogle Scholar
  18. 18.
    SMART and SAINT. Release 5.0. Area Detector Control and Integration Software, Bruker AXS, Madison: Analytical X-ray Instruments, 1998.Google Scholar
  19. 19.
    Sheldrick, G.M., SADABS. A Program for Exploiting the Redundancy of Area-Detector X-ray Data, Göttingen: Univ. of Göttingen, 1999.Google Scholar
  20. 20.
    Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, no. 1, p. 112.CrossRefGoogle Scholar
  21. 21.
    Spek, A.L., J. Appl. Crystallogr., 2003, vol. 36, p. 7.CrossRefGoogle Scholar
  22. 22.
    Batsanov, S.S., Neorg. Mater., 2001, vol. 37, no. 9, p. 1031.Google Scholar
  23. 23.
    Alvarez, S., Dalton Trans., 2013, vol. 42, no. 24, p. 8617.CrossRefGoogle Scholar
  24. 24.
    Hu, S.-Z., Zhou, Z.-H., and Robertson, B.E., Z. Kristallogr., 2009, vol. 224, no. 8, p. 375.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • Yu. P. Tupolova
    • 1
    Email author
  • S. I. Levchenkov
    • 1
    • 2
  • L. D. Popov
    • 1
  • S. V. Posokhova
    • 3
  • A. A. Aleksandrov
    • 4
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Scientific Center, Russian Academy of SciencesRostov-on-DonRussia
  3. 3.Azov Black Sea Engineering Institute, Don State Agrarian UniversityZernogradRussia
  4. 4.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia

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