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Coordination Polymers of Zn and Cd Based on Two Isomeric Azine Ligands: Synthesis, Crystal Structures, and Luminescence Properties

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Abstract

Metal-organic 1D coordination polymers of Zn(II) and Cd(II), [{Zn(3-Bphz)(H2O)4}(3-Bphz)(NO3)2]n (I), [Zn(3-Bphz)I2]n (II), [Cd(3-Bphz)I2]n (III), [Cd(4-Bphz)(CH3COO)2(H2O)]n (IV), and [Cd(4-Bphz)(NO3)2(H2O)2]n (V), containing azines of the N,N' type, 1,2-bis(pyridin-3-ylmethylene)hydrazine (3-Bphz) and 1,2-bis(pyridin-4-ylmethylene)hydrazine (4-Bphz), as bridging ligands are synthesized. The compositions and structures of the compounds are confirmed by the data of elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction analysis (CIF files CCDC nos. 1812634–1812638 for I–V). Coordination polymers I–III have zigzag structures. The octahedral environment of the Zn2+ ion in compound I is formed by two 3-Bphz ligands and four water molecules. The external sphere contains nitrate anions and uncoordinated 3-Bphz molecules. In isomorphous compounds II and III, the tetrahedral environment of the metal is formed by two nitrogen atoms of two bridging 3-Bphz ligands and two iodine atoms. Coordination polymers IV and V are linear. The coordination polyhedron of the Cd2+ ion in compound IV is a pentagonal bipyramid, two vertices of which are occupied by the nitrogen atoms of two 4-Bphz molecules, and the equatorial plane is formed by two bidentate-chelating acetate anions and one water molecule. In compound V, the octahedral environment of the Сd2+ ion is formed by two molecules of the 4-Bphz ligand, two monodentate nitrate anions, and two water molecules. All complexes are weak luminophores emitting in the blue-green spectral range.

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Authors and Affiliations

  1. Institute of Chemistry, Chisinau, Republic of Moldova

    V. Lozovan & E. B. Coropceanu

  2. Tiraspol State University, Chisinau, Republic of Moldova

    V. Lozovan, E. B. Coropceanu & P. N. Bourosh

  3. Institute of Applied Physics, Chisinau, Republic of Moldova

    P. N. Bourosh, A. Micu & M. S. Fonari

Authors
  1. V. Lozovan
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  2. E. B. Coropceanu
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  3. P. N. Bourosh
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  4. A. Micu
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  5. M. S. Fonari
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Correspondence to E. B. Coropceanu or M. S. Fonari.

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Translated by E. Yablonskaya

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Lozovan, V., Coropceanu, E.B., Bourosh, P.N. et al. Coordination Polymers of Zn and Cd Based on Two Isomeric Azine Ligands: Synthesis, Crystal Structures, and Luminescence Properties. Russ J Coord Chem 45, 11–21 (2019). https://doi.org/10.1134/S107032841901007X

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  • DOI: https://doi.org/10.1134/S107032841901007X

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