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Structural Diversity of Two Coordination Polymers based on Bis(4-(1H-imidazol-1-yl)phenyl)methanone and Polycarboxylate Coligands: Syntheses, Structures, and Fluorescent Properties

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Abstract

Two novel coordination polymers, [Zn2(Bipmo)2(Adip)2 · 2H2O]n (I), [Zn(Bipmo)(Adip) · 2H2O]n (II) (Bipmo = bis(4-(1H-imidazol-1-yl)phenyl)methanone, H2Adip = adipic acid) with unprecedented structures, have been synthesized and structurally characterized. by single-crystal X-raydiffraction (CIF files CCDC nos. 1555292 (I), 1555289 (II)). Complex I exhibits 4-fold interpenetrating wave-like sheets, which interpenetrate in a 2D → 2D parallel manner and pillar to generate 3D architectures. Complex II consists of a 2-fold 4-connected 3D coordination polymers network with a point symbol of (65.8). The results indicate that the central metal ions, polycarboxylate and semirigid co-ligands have a great effect on the formation and the structures of the coordination polymers. Moreover, the thermal stability and the luminescent properties of complexes I, II were investigated.

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Authors and Affiliations

  1. Department of Applied Chemistry, Yuncheng University, , 044000, Yuncheng, P.R. China

    G. F. Wang

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  1. G. F. Wang
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Correspondence to G. F. Wang.

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Wang, G.F. Structural Diversity of Two Coordination Polymers based on Bis(4-(1H-imidazol-1-yl)phenyl)methanone and Polycarboxylate Coligands: Syntheses, Structures, and Fluorescent Properties. Russ J Coord Chem 44, 540–546 (2018). https://doi.org/10.1134/S1070328418090075

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  • DOI: https://doi.org/10.1134/S1070328418090075

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