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Synthesis and Crystal Structure of Binuclear Half-Sandwich Rhodium Carborane Complex

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Abstract

Reaction of unsaturated 16e half-sandwich rhodium carborane complex [Cp*Rh(S2C2B10H10)] (Cp* = pentamethyl-cyclopentadienyl) with half equiv. (m-pyridyl)N=C(C10H6)C=N(m-pyridyl) (mPy-Bian, L) afforded a bi-nuclear complex [{Cp*Rh(S2C2B10H10)}2(μ-L)] (I), leaving α-diimine moiety of the L ligand as free coordination site. Compounds L and I have been characterized by single crystal X-ray diffraction (CIF files nos. 1586584 (L) and 1586585 (I)). Compound L crystallizes in the monoclinic space group C2/c with a = 21.51(3), b = 8.884(13), c = 9.414(14) Å, β = 112.540(19)°, and Z = 4. Complex I crystallizes in the orthorhombic space group Pnma with a = 15.741(2), b = 34.062(5), c = 14.960(2) Å, and Z = 4.

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Authors and Affiliations

  1. Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, 243002, Ma’anshan, Anhui, P.R. China

    A. Q. Jia, D. Liu, D. W. Fang & Z. Qian

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  1. A. Q. Jia
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  2. D. Liu
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  3. D. W. Fang
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  4. Z. Qian
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Correspondence to A. Q. Jia.

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Jia, A.Q., Liu, D., Fang, D.W. et al. Synthesis and Crystal Structure of Binuclear Half-Sandwich Rhodium Carborane Complex. Russ J Coord Chem 44, 559–564 (2018). https://doi.org/10.1134/S1070328418090038

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