Advertisement

Russian Journal of Coordination Chemistry

, Volume 44, Issue 6, pp 410–414 | Cite as

Spontaneous Association of the Terbium Cyclopentadienyl Complexes under Controlled Hydrolysis

  • D. M. Roitershtein
  • M. D. Dobrokhodov
  • A. A. Vinogradov
  • M. E. Minyaev
  • K. A. Lyssenko
  • A. V. Churakov
  • N. P. Datskevich
  • I. V. Taidakov
  • I. E. Nifant’ev
Article
  • 10 Downloads

Abstract

Controlled hydrolysis of the terbium cyclopentadienyl complexes results in the formation of the heteroligand tetranuclear terbium complex [{Tb(η5-C5H5)}3{Tb(THF)3}(μ3-Cl)(μ2-Cl)64-O)] (I), the recrystallization of which from tetrahydrofuran (THF) gives solvatomorph I · 0.5THF (Ia). According to the X-ray structure analysis data (CIF files CCDC 1569329 (I) and 1569330 (Ia)), the complexes are tetrahedral with the μ4-bridging O2– anion at the center of the tetrahedron. The cyclopentadienyl ligand in complex I is shown to act as an “antenna” providing luminescence of the complex.

Keywords

rare-earth metals X-ray structure analysis luminescence cyclopentadienyl ligand 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Wilkinson, G. and Birmingham, J.M., J. Am. Chem. Soc., 1954, vol. 76, no. 23, p. 6210.CrossRefGoogle Scholar
  2. 2.
    Birmingham, J.M. and Wilkinson, G., J. Am. Chem. Soc., 1956, vol. 78, no. 1, p. 42.CrossRefGoogle Scholar
  3. 3.
    Maginn, R.E., Manasturskyj, S., and Dubeck, M.J., J. Am. Chem. Soc., 1963, vol. 85, no. 6, p. 672.CrossRefGoogle Scholar
  4. 4.
    Manastyrskyj, S., Maginn, R.E., and Dubeck, M., Inorg. Chem., 1963, vol. 2, no. 5, p. 904.CrossRefGoogle Scholar
  5. 5.
    Edelmann, F.T., in Comprehensive Organometallic Chemistry III, Mingos, D., Michael, P., and Crabtree, R.H., Eds., 2007, vol. 4, p. 1.Google Scholar
  6. 6.
    Anwander, R., Organomet. Chem., 1999, vol. 2, p. 1.Google Scholar
  7. 7.
    Evans, W.J., Inorg. Chem., 2007, vol. 46, p. 3435.CrossRefPubMedGoogle Scholar
  8. 8.
    Evans, W.J., Polyhedron, 1987, vol. 6, p. 803.CrossRefGoogle Scholar
  9. 9.
    Yanga, H., Jones, R., and Huanga, S., Coord. Chem. Rev., 2014, vols. 273−274, p. 63.CrossRefGoogle Scholar
  10. 10.
    Fomina, I.G., Dobrokhotova, Zh.V., Kazak, V.O., et al., Eur. J. Inorg. Chem., 2012, no. 22, p. 3595.CrossRefGoogle Scholar
  11. 11.
    Boyle, T.J. and Ottley, L.A.M., Chem. Rev., 2008, vol. 108, p. 1896.CrossRefPubMedGoogle Scholar
  12. 12.
    Herrmann, W.A. and Edelmann, F.T., Synthetic Methods of Organometallic and Inorganic Chemistry, Stuttgart: Georg Thiere, 1997, vol. 6.Google Scholar
  13. 13.
    Panda, T.K., Gamer, M.T., and Roesky, P.W., Organometallics, 2003, vol. 22, p. 877.CrossRefGoogle Scholar
  14. 14.
    Cambridge Structural Database System, Version 5.38, 2016.Google Scholar
  15. 15.
    Roitershtein, D.M., Minyaev, M.E., Mikhaylyuk, A.A., et al., Russ. Chem. Bull. Int. Ed., 2012, vol. 61, p. 1726.CrossRefGoogle Scholar
  16. 16.
    Jin, J.-Z., Wei, G.-C., Jin, Z.-S., and Chen, W.-Q., Jiegou Huaxue (Chin. J. Struct. Chem.), 1992, vol. 11, p. 369.Google Scholar
  17. 17.
    Zhou, X., Ma, H., Wu, Z., You, X., Xu, Z., and Huang, X., J. Organomet.Chem., 1995, vol. 503, p. 11.CrossRefGoogle Scholar
  18. 18.
    Bünzli, J.-C.G. and Eliseeva, S.V., in Lanthanide Luminescence: Photophysical, Analytical and Biological Aspects, Hänninen, P. and Härmä, H., Eds., Berlin: Springer, 2011, p. 1.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • D. M. Roitershtein
    • 1
    • 2
  • M. D. Dobrokhodov
    • 1
  • A. A. Vinogradov
    • 1
  • M. E. Minyaev
    • 1
  • K. A. Lyssenko
    • 3
  • A. V. Churakov
    • 4
  • N. P. Datskevich
    • 5
  • I. V. Taidakov
    • 3
    • 5
  • I. E. Nifant’ev
    • 1
    • 6
  1. 1.Topchiev Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussia
  2. 2.Zelinskii Institute of Organic ChemistryRussian Academy of SciencesMoscowRussia
  3. 3.Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia
  4. 4.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  5. 5.Lebedev Physical InstituteRussian Academy of SciencesMoscowRussia
  6. 6.Moscow State UniversityMoscowRussia

Personalised recommendations