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Synthesis and Structure of Different-Metal Different-Ligand Germanium(IV) and Cobalt(II) or Copper(II) Complexes with 1-Hydroxyethylidenediphosphonic Acid and 1,10-Phenanthroline

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Abstract

Different-metal different-ligand complexes [{Co(Phen)3}2{Co(Phen)(H2O)4}2][{Ge(μ-OH)(μ- Hedp)}6Cl2] (I), [{Cu(Phen)2(H2O)}2(HPhen)2][Ge(μ-OH)(μ-Hedp)]6 · 20H2O (II) (H4Hedp = 1-hydroxyethylidenediphosphonic acid, Phen = 1,10-phenanthroline) were synthesized and studied by X-ray diffraction. According to X-ray diffraction data (CIF files CCDC nos. 1573112 (I), 1573113 (II)), compounds I and II are cation–anion type complexes in which the anions are represented by {[Ge(μ-OH)(μ-Hedp)]6}6– and, in the case of I, two additional Cl– ions, while the cations are [Co(Phen)3]2+, [Co(Phen)(H2O)4]2+ in I and [Cu(Phen)2(H2O)]2+, HPhen+ in II. In the crystals of compounds I and II, the cations, anions, and water molecules are combined by numerous intermolecular hydrogen bonds, giving rise to a 3D network.

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Authors and Affiliations

  1. Odessa Mechnikov National University, Odessa, 65082, Ukraine

    E. E. Martsinko, I. I. Seifullina, E. A. Chebanenko & N. M. Khristova

  2. State Scientific Institution Institute for Single Crystals, National Academy of Sciences of Ukraine, Kharkiv, 61001, Ukraine

    V. V. Dyakonenko & S. V. Shishkina

  3. Karazin Kharkiv National University, Kharkiv, 61022, Ukraine

    S. V. Shishkina

Authors
  1. E. E. Martsinko
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  2. I. I. Seifullina
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  3. E. A. Chebanenko
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  4. V. V. Dyakonenko
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  5. S. V. Shishkina
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  6. N. M. Khristova
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Corresponding author

Correspondence to E. E. Martsinko.

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Original Russian Text © E.E. Martsinko, I.I. Seifullina, E.A. Chebanenko, V.V. Dyakonenko, S.V. Shishkina, N.M. Khristova, 2018, published in Koordinatsionnaya Khimiya, 2018, Vol. 44, No. 3, pp. 189–195.

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Martsinko, E.E., Seifullina, I.I., Chebanenko, E.A. et al. Synthesis and Structure of Different-Metal Different-Ligand Germanium(IV) and Cobalt(II) or Copper(II) Complexes with 1-Hydroxyethylidenediphosphonic Acid and 1,10-Phenanthroline. Russ J Coord Chem 44, 393–399 (2018). https://doi.org/10.1134/S1070328418060039

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  • DOI: https://doi.org/10.1134/S1070328418060039

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