Skip to main content
Log in

Binuclear Cyclic Silver(I) Complex with the Anion of 4-[(2-Diphenylphosphanylphenyl)methyleneamino]benzoic Acid: Synthesis, Structure, and Optical Properties

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

4-[(2-Diphenylphosphanylphenyl)methyleneamino]benzoic acid (HL) is obtained by the condensation of o-diphenylphosphinobenzaldehyde and p-aminobenzoic acid. The reaction of AgNO3 and HL affords complex [Ag2L2] · H2O (I). The structure of complex I is determined by X-ray structure analysis (CIF file CCDC 1575064), and its reflectance and luminescence spectra are studied. Binuclear complex I is a cyclic molecule in which each of two silver(I) atoms coordinates one phosphorus atom and one oxygen atom of two bridging anions L. Compound I is characterized by emission in a range of 430–740 nm at λexc = 340 and 395 nm.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Pomogailo, A.D. and Dzhardimalieva, G.I. Monomernye i polimernye karboksilaty metallov (Monomeric and Polymeric Metal Carboxylates), Moscow: Fizmat, 2009.

    Google Scholar 

  2. Kiskin, M.A. and Eremenko, I.L., Usp. Khim., 2006, vol. 75, p. 627.

    Article  CAS  Google Scholar 

  3. Metal Complexes and Metals in Macromolecules, Wohrle, D. and Pomogailo, A.D., Eds., New York: Wiley, 2003.

    Google Scholar 

  4. Ling, Q.D., Cai, Q.L., Kang, E.T., et al., Mater. Chem., 2004, vol. 14, p. 2741.

    Article  CAS  Google Scholar 

  5. Ling, Q.D., Yang, M., Wu, Z., et al., Polymer, 2001, vol. 42, p. 4605.

    Article  CAS  Google Scholar 

  6. Lu, X., Ye, J., Zhang, D., et al., J. Inorg. Biochem., 2014, vol. 138, p. 114.

    Article  CAS  PubMed  Google Scholar 

  7. Dobrohotova, Zh.V., Sidorov, A.A., Kiskin, M.A., et al., J. Solid State Chem., 2010, vol. 183, p. 2475.

    Article  CAS  Google Scholar 

  8. Abdulwahab, K.O., Malik, M.A., O’Brien, P., et al., Chem. Mater., 2016, vol. 26, p. 999.

    Article  CAS  Google Scholar 

  9. Kokunov, Yu.V., Gorbunova, Yu.E., Popov, L.D., et al., Russ. J. Coord. Chem., 2016, vol. 42, no. 6, p. 361.

    Article  CAS  Google Scholar 

  10. Kole, G.K., Tan, G.K., and Vittal, J.J., Cryst. Growth Des., 2012, vol. 12, p. 326.

    Article  CAS  Google Scholar 

  11. SMART (control) and SAINT (integration) Software. Version 5.0, Madison: Bruker AXS Inc., 1997.

  12. Sheldrick, G.M., SADABS. Program for Scanning and Correction of Area Detector Data, Göttingen: Univ. of Göttingen, 2004.

    Google Scholar 

  13. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.

    Article  CAS  Google Scholar 

  14. Nomiya, K. and Yokoyama, H., Dalton Trans., 2002, p. 2483.

    Google Scholar 

  15. Molecular Structure by Diffraction Methods, Sim, G.A. and Sutton, L.E., Eds., London: Chemical Society, 1972.

    Google Scholar 

  16. Nakamoto, K., Infrared Spectra and Raman Spectra of Inorganic and Coordination Compounds, New York: Wiley, 1986.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. V. Kovalev.

Additional information

Original Russian Text © Yu.V. Kokunov, V.V. Kovalev, M.A. Kiskin, S.A. Borodkin, L.D. Popov, I.L. Eremenko, 2018, published in Koordinatsionnaya Khimiya, 2018, Vol. 44, No. 3, pp. 184–188.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kokunov, Y.V., Kovalev, V.V., Kiskin, M.A. et al. Binuclear Cyclic Silver(I) Complex with the Anion of 4-[(2-Diphenylphosphanylphenyl)methyleneamino]benzoic Acid: Synthesis, Structure, and Optical Properties. Russ J Coord Chem 44, 388–392 (2018). https://doi.org/10.1134/S1070328418060027

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328418060027

Keywords

Navigation