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Binuclear Cyclic Silver(I) Complex with the Anion of 4-[(2-Diphenylphosphanylphenyl)methyleneamino]benzoic Acid: Synthesis, Structure, and Optical Properties

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4-[(2-Diphenylphosphanylphenyl)methyleneamino]benzoic acid (HL) is obtained by the condensation of o-diphenylphosphinobenzaldehyde and p-aminobenzoic acid. The reaction of AgNO3 and HL affords complex [Ag2L2] · H2O (I). The structure of complex I is determined by X-ray structure analysis (CIF file CCDC 1575064), and its reflectance and luminescence spectra are studied. Binuclear complex I is a cyclic molecule in which each of two silver(I) atoms coordinates one phosphorus atom and one oxygen atom of two bridging anions L. Compound I is characterized by emission in a range of 430–740 nm at λexc = 340 and 395 nm.

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Correspondence to V. V. Kovalev.

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Original Russian Text © Yu.V. Kokunov, V.V. Kovalev, M.A. Kiskin, S.A. Borodkin, L.D. Popov, I.L. Eremenko, 2018, published in Koordinatsionnaya Khimiya, 2018, Vol. 44, No. 3, pp. 184–188.

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Kokunov, Y.V., Kovalev, V.V., Kiskin, M.A. et al. Binuclear Cyclic Silver(I) Complex with the Anion of 4-[(2-Diphenylphosphanylphenyl)methyleneamino]benzoic Acid: Synthesis, Structure, and Optical Properties. Russ J Coord Chem 44, 388–392 (2018).

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