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Russian Journal of Coordination Chemistry

, Volume 44, Issue 6, pp 388–392 | Cite as

Binuclear Cyclic Silver(I) Complex with the Anion of 4-[(2-Diphenylphosphanylphenyl)methyleneamino]benzoic Acid: Synthesis, Structure, and Optical Properties

  • Yu. V. Kokunov
  • V. V. Kovalev
  • M. A. Kiskin
  • S. A. Borodkin
  • L. D. Popov
  • I. L. Eremenko
Article
  • 11 Downloads

Abstract

4-[(2-Diphenylphosphanylphenyl)methyleneamino]benzoic acid (HL) is obtained by the condensation of o-diphenylphosphinobenzaldehyde and p-aminobenzoic acid. The reaction of AgNO3 and HL affords complex [Ag2L2] · H2O (I). The structure of complex I is determined by X-ray structure analysis (CIF file CCDC 1575064), and its reflectance and luminescence spectra are studied. Binuclear complex I is a cyclic molecule in which each of two silver(I) atoms coordinates one phosphorus atom and one oxygen atom of two bridging anions L. Compound I is characterized by emission in a range of 430–740 nm at λexc = 340 and 395 nm.

Keywords

Schiff bases silver complex structure luminescence properties 

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References

  1. 1.
    Pomogailo, A.D. and Dzhardimalieva, G.I. Monomernye i polimernye karboksilaty metallov (Monomeric and Polymeric Metal Carboxylates), Moscow: Fizmat, 2009.Google Scholar
  2. 2.
    Kiskin, M.A. and Eremenko, I.L., Usp. Khim., 2006, vol. 75, p. 627.CrossRefGoogle Scholar
  3. 3.
    Metal Complexes and Metals in Macromolecules, Wohrle, D. and Pomogailo, A.D., Eds., New York: Wiley, 2003.Google Scholar
  4. 4.
    Ling, Q.D., Cai, Q.L., Kang, E.T., et al., Mater. Chem., 2004, vol. 14, p. 2741.CrossRefGoogle Scholar
  5. 5.
    Ling, Q.D., Yang, M., Wu, Z., et al., Polymer, 2001, vol. 42, p. 4605.CrossRefGoogle Scholar
  6. 6.
    Lu, X., Ye, J., Zhang, D., et al., J. Inorg. Biochem., 2014, vol. 138, p. 114.CrossRefGoogle Scholar
  7. 7.
    Dobrohotova, Zh.V., Sidorov, A.A., Kiskin, M.A., et al., J. Solid State Chem., 2010, vol. 183, p. 2475.CrossRefGoogle Scholar
  8. 8.
    Abdulwahab, K.O., Malik, M.A., O’Brien, P., et al., Chem. Mater., 2016, vol. 26, p. 999.CrossRefGoogle Scholar
  9. 9.
    Kokunov, Yu.V., Gorbunova, Yu.E., Popov, L.D., et al., Russ. J. Coord. Chem., 2016, vol. 42, no. 6, p. 361.CrossRefGoogle Scholar
  10. 10.
    Kole, G.K., Tan, G.K., and Vittal, J.J., Cryst. Growth Des., 2012, vol. 12, p. 326.CrossRefGoogle Scholar
  11. 11.
    SMART (control) and SAINT (integration) Software. Version 5.0, Madison: Bruker AXS Inc., 1997.Google Scholar
  12. 12.
    Sheldrick, G.M., SADABS. Program for Scanning and Correction of Area Detector Data, Göttingen: Univ. of Göttingen, 2004.Google Scholar
  13. 13.
    Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.CrossRefGoogle Scholar
  14. 14.
    Nomiya, K. and Yokoyama, H., Dalton Trans., 2002, p. 2483.Google Scholar
  15. 15.
    Molecular Structure by Diffraction Methods, Sim, G.A. and Sutton, L.E., Eds., London: Chemical Society, 1972.Google Scholar
  16. 16.
    Nakamoto, K., Infrared Spectra and Raman Spectra of Inorganic and Coordination Compounds, New York: Wiley, 1986.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • Yu. V. Kokunov
    • 1
  • V. V. Kovalev
    • 1
  • M. A. Kiskin
    • 1
  • S. A. Borodkin
    • 2
  • L. D. Popov
    • 2
  • I. L. Eremenko
    • 1
  1. 1.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  2. 2.Southern Federal UniversityRostov-on-DonRussia

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