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Russian Journal of Coordination Chemistry

, Volume 44, Issue 6, pp 373–379 | Cite as

1D-Bromobismuthates of Dipyridinoalkane Derivatives

  • P. A. Buikin
  • A. Yu. Rudenko
  • A. E. Baranchikov
  • A. B. Ilyukhin
  • V. Yu. Kotov
Article

Abstract

The following bromobismuthates of organic cations (dipyridinoalkane derivatives) are synthesized and characterized: (4-NH2PyC5)BiBr5 (I), (2-MePyC2)BiBr5 (II), (2-NH2PyC10)BiBr5 · 0.65H2O (III), (2-NH2PyC10)4H5O2(BiBr6)3 (IV), (2-NH2PyС6)2KBi2Br11 (V), (2-NH2PyC6)H3OBiBr6 · 2.33H2O (VI), and (2-NH2PyC6)3(BiBr6)2 · CH3CN (VII). Three compounds obtained (I–III) contain the zigzag 1D chain (BiBr5) n . A new type of 1D chains, (KBi2Br11) n , is found in the structure of compound V. Pseudo-1D chains of BiBr63− anions can be observed in the 3D structures of compounds IV, VI, and VII. The crystallographic data were deposited with the Cambridge Crystallographic Data Centre (CIF files CCDC 1569478 (I)–1569484 (VII), respectively).

Keywords

hybrid bromobismuthates crystal structure optical properties polynuclear chains 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • P. A. Buikin
    • 1
    • 2
  • A. Yu. Rudenko
    • 2
  • A. E. Baranchikov
    • 1
  • A. B. Ilyukhin
    • 1
  • V. Yu. Kotov
    • 1
    • 2
  1. 1.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  2. 2.Mendeleev University of Chemical TechnologyMoscowRussia

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