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Crystal Structure of the Polymer Copper(II) Complex with 1-Phenyl-3-Methyl-4-Formyl-5-Hydroxypyrazole Hetarylhydrazone

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Abstract

A new coordination polymer of Cu(II) based on 1-phenyl-3-methyl-4-formyl-5-hydroxypyrazole 4,6-dimethylpyrimidylhydrazone is synthesized. The polymer is studied by X-ray diffraction analysis (CIF file CCDC no. 1565772). It is shown that the polymer is formed due to the coordination of the nitrogen atom of the pyrazolone fragment to the copper(II) ion of the adjacent monomeric fragment.

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References

  1. Lukov, V.V., Kogan, V.A., Levchenkov, S.I., et al., Russ. J. Coord. Chem., 2015, vol. 41, no. 1, p.1.

    Article  CAS  Google Scholar 

  2. Minkin, V.I., Izv. Akad. Nauk, Ser. Khim., 2008, vol. 57, no. 4, p.673.

    Google Scholar 

  3. Kahn, O., Acc. Chem. Res., 2000, vol. 33, no. 10, p.647.

    Article  CAS  Google Scholar 

  4. Dul, M.-C., Pardo, E., Lescouezec, R., et al., Coord. Chem. Rev., 2010, vol. 254, p. 2281.

    Article  CAS  Google Scholar 

  5. Leuenberger, M.N. and Loss, D., Nature, 2001, vol. 410, p.789.

    Article  CAS  Google Scholar 

  6. Zhang, L., Liu, L., Jia, D., and Yu, K., Struct. Chem., 2004, vol. 15, no. 4, p.327.

    Article  Google Scholar 

  7. Yang, Y., Zhang, L., Liu, L., et al., Inorg. Chim. Acta, 2007, vol. 360, p. 2638.

    Article  CAS  Google Scholar 

  8. Li, H.-G., Yang, Z.-Y., and Qin, D.-D., Inorg. Chem. Commun., 2009, vol. 12, p.494.

    Article  CAS  Google Scholar 

  9. Zhang, L., Liu, L., Jia, D., et al., Inorg. Chem. Commun., 2004, vol. 7, p. 1306.

    Article  CAS  Google Scholar 

  10. Zhan, L., Liu, L., Xu, G.-C., and Jia, D.-Z., J. Chem. Crystallogr., 2008, vol. 38, p.837.

    Article  Google Scholar 

  11. Hu, X., Zhang, L., Liu, L., et al., Inorg. Chim. Acta, 2006, vol. 359, p.633.

    Article  CAS  Google Scholar 

  12. Zhang, Y., Zhang, L., Liu, L., et al., Inorg. Chim. Acta, 2010, vol. 363, p.289.

    Article  CAS  Google Scholar 

  13. Levchenkov, S.I., Shcherbakov, I.N., Popov, L.D., et al., Inorg. Chim. Acta, 2013, vol. 405, p.169.

    Article  CAS  Google Scholar 

  14. Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N., et al., Russ. J. Coord. Chem., 2013, vol. 39, no. 12, p.849.

    Article  CAS  Google Scholar 

  15. Yi, L.-J., Xu, G.-C., Zhang, L., and Jia, D.-Z., Inorg. Chem. Commun., 2014, vol. 45, p.36.

    Article  CAS  Google Scholar 

  16. Liu, L., Li, Y., Jia, D.-Z., et al., J. Inorg. Organomet. Polym. Mater., 2007, vol. 17, no. 3, p.535.

    Article  CAS  Google Scholar 

  17. Porai-Koshits, B.A. and Kvitko, I.Ya., Zh. Obshch. Khim., 1964, vol. 34, no. 9, p. 2995.

    Google Scholar 

  18. Kosolapoff, G.M. and Roy, C.H., Org. Chem., 1961, vol. 26, p. 1895.

    Article  CAS  Google Scholar 

  19. Sheldrick, G.M., SHELXTL. Version. 6.14. Structure Determination Software Suite, Madison: Bruker AXS, 2000.

    Google Scholar 

  20. Addison, A.W., Rao, T.N., Reedijk, J., et al., J. Chem. Soc., Dalton Trans., 1984, no. 7, p. 1349.

    Article  Google Scholar 

  21. Groom, C.R., Bruno, I.J., Lightfoot, M.P., and Ward, S.C., Acta Crystallogr., Sect. B: Struct. Sci., Cryst. Eng. Mater., 2016, vol. 72, no. 2, p.171.

    Article  CAS  Google Scholar 

  22. Zhang, L., Xu, G.-C., Yang, Y., et al., Dalton Trans., 2013, vol. 42, no. 12, p. 4248.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Southern Federal University, Rostov-on-Don, Russia

    Yu. P. Tupolova, I. N. Shcherbakov, L. D. Popov, S. I. Levchenkov & V. A. Chetverikova

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. V. Tkachev, G. V. Shilov & S. M. Aldoshin

  3. Southern Research Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    S. I. Levchenkov

Authors
  1. Yu. P. Tupolova
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  2. I. N. Shcherbakov
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  3. V. V. Tkachev
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  4. L. D. Popov
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  5. S. I. Levchenkov
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  6. V. A. Chetverikova
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  7. G. V. Shilov
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  8. S. M. Aldoshin
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Corresponding author

Correspondence to I. N. Shcherbakov.

Additional information

Original Russian Text © Yu.P. Tupolova, I.N. Shcherbakov, V.V. Tkachev, L.D. Popov, S.I. Levchenkov, V.A. Chetverikova, G.V. Shilov, S.M. Aldoshin, 2018, published in Koordinatsionnaya Khimiya, 2018, Vol. 44, No. 1, pp. 43–48.

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Tupolova, Y.P., Shcherbakov, I.N., Tkachev, V.V. et al. Crystal Structure of the Polymer Copper(II) Complex with 1-Phenyl-3-Methyl-4-Formyl-5-Hydroxypyrazole Hetarylhydrazone. Russ J Coord Chem 44, 132–137 (2018). https://doi.org/10.1134/S1070328418020112

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  • DOI: https://doi.org/10.1134/S1070328418020112

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