Advertisement

Russian Journal of Coordination Chemistry

, Volume 44, Issue 2, pp 132–137 | Cite as

Crystal Structure of the Polymer Copper(II) Complex with 1-Phenyl-3-Methyl-4-Formyl-5-Hydroxypyrazole Hetarylhydrazone

  • Yu. P. Tupolova
  • I. N. Shcherbakov
  • V. V. Tkachev
  • L. D. Popov
  • S. I. Levchenkov
  • V. A. Chetverikova
  • G. V. Shilov
  • S. M. Aldoshin
Article
  • 26 Downloads

Abstract

A new coordination polymer of Cu(II) based on 1-phenyl-3-methyl-4-formyl-5-hydroxypyrazole 4,6-dimethylpyrimidylhydrazone is synthesized. The polymer is studied by X-ray diffraction analysis (CIF file CCDC no. 1565772). It is shown that the polymer is formed due to the coordination of the nitrogen atom of the pyrazolone fragment to the copper(II) ion of the adjacent monomeric fragment.

Keywords

coordination compounds coordination polymers X-ray diffraction analysis 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Lukov, V.V., Kogan, V.A., Levchenkov, S.I., et al., Russ. J. Coord. Chem., 2015, vol. 41, no. 1, p.1.CrossRefGoogle Scholar
  2. 2.
    Minkin, V.I., Izv. Akad. Nauk, Ser. Khim., 2008, vol. 57, no. 4, p.673.Google Scholar
  3. 3.
    Kahn, O., Acc. Chem. Res., 2000, vol. 33, no. 10, p.647.CrossRefGoogle Scholar
  4. 4.
    Dul, M.-C., Pardo, E., Lescouezec, R., et al., Coord. Chem. Rev., 2010, vol. 254, p. 2281.CrossRefGoogle Scholar
  5. 5.
    Leuenberger, M.N. and Loss, D., Nature, 2001, vol. 410, p.789.CrossRefGoogle Scholar
  6. 6.
    Zhang, L., Liu, L., Jia, D., and Yu, K., Struct. Chem., 2004, vol. 15, no. 4, p.327.CrossRefGoogle Scholar
  7. 7.
    Yang, Y., Zhang, L., Liu, L., et al., Inorg. Chim. Acta, 2007, vol. 360, p. 2638.CrossRefGoogle Scholar
  8. 8.
    Li, H.-G., Yang, Z.-Y., and Qin, D.-D., Inorg. Chem. Commun., 2009, vol. 12, p.494.CrossRefGoogle Scholar
  9. 9.
    Zhang, L., Liu, L., Jia, D., et al., Inorg. Chem. Commun., 2004, vol. 7, p. 1306.CrossRefGoogle Scholar
  10. 10.
    Zhan, L., Liu, L., Xu, G.-C., and Jia, D.-Z., J. Chem. Crystallogr., 2008, vol. 38, p.837.CrossRefGoogle Scholar
  11. 11.
    Hu, X., Zhang, L., Liu, L., et al., Inorg. Chim. Acta, 2006, vol. 359, p.633.CrossRefGoogle Scholar
  12. 12.
    Zhang, Y., Zhang, L., Liu, L., et al., Inorg. Chim. Acta, 2010, vol. 363, p.289.CrossRefGoogle Scholar
  13. 13.
    Levchenkov, S.I., Shcherbakov, I.N., Popov, L.D., et al., Inorg. Chim. Acta, 2013, vol. 405, p.169.CrossRefGoogle Scholar
  14. 14.
    Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N., et al., Russ. J. Coord. Chem., 2013, vol. 39, no. 12, p.849.CrossRefGoogle Scholar
  15. 15.
    Yi, L.-J., Xu, G.-C., Zhang, L., and Jia, D.-Z., Inorg. Chem. Commun., 2014, vol. 45, p.36.CrossRefGoogle Scholar
  16. 16.
    Liu, L., Li, Y., Jia, D.-Z., et al., J. Inorg. Organomet. Polym. Mater., 2007, vol. 17, no. 3, p.535.CrossRefGoogle Scholar
  17. 17.
    Porai-Koshits, B.A. and Kvitko, I.Ya., Zh. Obshch. Khim., 1964, vol. 34, no. 9, p. 2995.Google Scholar
  18. 18.
    Kosolapoff, G.M. and Roy, C.H., Org. Chem., 1961, vol. 26, p. 1895.CrossRefGoogle Scholar
  19. 19.
    Sheldrick, G.M., SHELXTL. Version. 6.14. Structure Determination Software Suite, Madison: Bruker AXS, 2000.Google Scholar
  20. 20.
    Addison, A.W., Rao, T.N., Reedijk, J., et al., J. Chem. Soc., Dalton Trans., 1984, no. 7, p. 1349.CrossRefGoogle Scholar
  21. 21.
    Groom, C.R., Bruno, I.J., Lightfoot, M.P., and Ward, S.C., Acta Crystallogr., Sect. B: Struct. Sci., Cryst. Eng. Mater., 2016, vol. 72, no. 2, p.171.CrossRefGoogle Scholar
  22. 22.
    Zhang, L., Xu, G.-C., Yang, Y., et al., Dalton Trans., 2013, vol. 42, no. 12, p. 4248.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • Yu. P. Tupolova
    • 1
  • I. N. Shcherbakov
    • 1
  • V. V. Tkachev
    • 2
  • L. D. Popov
    • 1
  • S. I. Levchenkov
    • 1
    • 3
  • V. A. Chetverikova
    • 1
  • G. V. Shilov
    • 2
  • S. M. Aldoshin
    • 2
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovkaRussia
  3. 3.Southern Research CenterRussian Academy of SciencesRostov-on-DonRussia

Personalised recommendations