Abstract
The formation conditions and luminescence of Tb(III) complexes with synthesized copolymers of unsaturated acetylacetone derivatives with styrene and methyl methacrylate were studied. The luminescence intensity of these Tb(III) complexes was found to depend on the β-diketone substituent nature (CH3, CF3, C6H5) and structure (linear, branched) and the β-diketone to monomer ratio in the polymerizing mixture.
Similar content being viewed by others
References
Problemy khimii i primeneniya ß-diketonatov metallov (Problems of Chemistry and Applications of Metal ß-Diketonates), Spitsyn, V.I., Ed., Moscow: Nauka, 1982.
Poluektov, N.S., Kononenko, L.I., Efryushina, N.P., et al., Spektrofotometricheskie i lyuminestsentnye metody opredeleniya lantanoidov (Spectrophotometric and Luminescent Methods for Determination of Lanthanides), Kiev: Naukova Dumka, 1989.
Katkova, M.A., Vitukhnovskii, A.G., and Bochkarev, M.N., Usp. Khim., 2005, vol. 74, no. 12, p. 193.
Binnemans, K., Rare-Earth Beta-Diketonates. Handbook on the Physics and Chemistry of Rare Earths, Gschneidner, K.A., Jr., Bünzli, J.-C.G., and Pecharsky, V.K., Eds., 2005, vol. 35, p. 190.
Binnemans, K., Chem. Rev., 2009, vol. 109, no. 9, p. 4283.
Eliseeva, S.V. and Bünzli, J.-C.G., Chem. Soc. Rev., 2010, vol. 39, p. 189.
Meshkova, S.B., J. Fluoresc., 2000, vol. 10, no. 4, p. 333.
Wang, L.-H., Wang, W., Zhang, W.-G., et al., Chem. Mater., 2000, vol. 12, no. 8, p. 2212.
Rozhkov, A.V., Bochkarev, L.N., Basova, G.V., et al., Russ. J. Gen. Chem., 2012, vol. 82, no. 12, p. 1937.
Yakimanskii, A.V., Goikhman, M.Ya., Podeshvo, I.V., et al., Vysokomol. Soed., 2012, vol. 54, no. 12, p. 1699.
Meshkova, S.B., Topilova, Z.M., Nazarenko, N.A., et al., J. Anal. Chem., 2000, vol. 55, no. 7, p. 676.
Meshkova, S.B., Shevchenko, O.V., Rudenko, T.P., et al., Ukr. Khim. Zh., 2014, vol. 80, no. 9, p. 26.
Ermolaev, V.L., Bodunov, E.N., Sveshnikova, E.B., and Shakhverdov, T.A., Bezyzluchatel’nyi perenos energii elektronnogo vozbuzhdeniya (Non-Radiative Electron Excitation Energy Transfer), Leningrad: Nauka, 1977.
Meshkova, S.B., Kiriyak, A.V., Topilova, Z.M., et al., Opt. Spektrosk., 2006, vol. 100, no. 6, p. 916.
Voloshanovskii, I.S., Shevchenko, O.V., Butova, T.D., et al., Russ. J. Appl. Chem., 2003, vol. 76, no. 2, p. 271.
Organikum: Organisch-chemisches Grundpraktikum, Berlin: VEB, 1976, vol. 2.
Babko, A.K. Fiziko-khimicheskii analiz kompleksnykh soedinenii v rastvorakh (Physicochemical Analysis of Complex Compounds in Solutions), Kiev: AN Ukr. SSR, 1955.
McGlynn, S., Azumi, T., and Kinoshita, M., Molecular Spectroscopy of the Triplet State, Prentice-Hall: Englewood Cliffs, 1969.
Meshkova, S.B., Topilova, Z.M., Kiriyak, A.V., and Chebotarskaya, I.I., Ukr. Khim. Zh., 2005, vol. 71. nos. 9-10, p. 12.
Ueba, Y., Banks, E., and Okamoto, Y., J. Appl. Polym. Sci., 1980, vol. 25, no. 11, p. 2007.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Meshkova, S.B., Shevchenko, O.V., Kovalenko, V.Y. et al. Effect of the Nature of the Polymer Matrix on the Luminescence of Tb(III) Complexes with β-Diketone Copolymers. Russ J Coord Chem 44, 220–225 (2018). https://doi.org/10.1134/S1070328418020070
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070328418020070