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Coordination Compounds of Silver Methanesulfonate with Triphenylphosphine and 1,2-Bis(4-Pyridyl)ethane

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Abstract

The reaction of Ag(CH3SO3) with PPh3 gave the compound [Ag(CH3SO3)(PPh3)2] (I) and the reaction of Ag(CH3SO3) with PPh3 and 1,2-bis(4-pyridyl)ethane (Dpe) affords the mixed complex [Ag(CH3SO3)(PPh3)(Dpe)] (II). The crystal structures of I and II were determined by X-ray diffraction (CIF file CCDC no. 1563357 (for I)). In I, the centrosymmetric binuclear complex [Ag(CH3SO3)-(PPh3)2]2 is formed. The Ag atom has a distorted tetrahedral coordination composed of two bidentate bridging O atoms of the sulfonate anion and two P atoms of two PPh3 ligands. The structure of II is based on the centrosymmetric binuclear molecule with two bridging Dpe ligands between two [Ag(CH3SO3)(PPh3)] complexes. The O atoms of the methanesulfonate ion are statistically disordered, which induces a considerable distortion of the silver polyhedron with C.N. 5. Both compounds tend to emit in the blue and green regions of the PL spectra.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 117907, Russia

    Yu. V. Kokunov, V. V. Kovalev, Yu. E. Gorbunova, S. A. Kozyukhin & G. A. Razgonyaeva

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  1. Yu. V. Kokunov
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  2. V. V. Kovalev
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  3. Yu. E. Gorbunova
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  4. S. A. Kozyukhin
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  5. G. A. Razgonyaeva
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Correspondence to V. V. Kovalev.

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Original Russian Text © Yu.V. Kokunov, V.V. Kovalev, Yu.E. Gorbunova, S.A. Kozyukhin, G.A. Razgonyaeva, 2018, published in Koordinatsionnaya Khimiya, 2018, Vol. 44, No. 1, pp. 14–19.

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Kokunov, Y.V., Kovalev, V.V., Gorbunova, Y.E. et al. Coordination Compounds of Silver Methanesulfonate with Triphenylphosphine and 1,2-Bis(4-Pyridyl)ethane. Russ J Coord Chem 44, 103–108 (2018). https://doi.org/10.1134/S1070328418020069

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  • DOI: https://doi.org/10.1134/S1070328418020069

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