Skip to main content
SpringerLink
Log in

Reactions of Chalcogenide β-Diiminate Nickel Complexes with Samarium Bis(pentamethylcyclopentadienide)

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The reactions of [(LiPrNi)2(μ-η2:η2-S4)] (I) and [(LiPrNi)2(μ-η2:η2-Se2)] (II) (LiPr = CH[C(Me)N(2,6-iPr2C6H3)]2) with decamethylsamarocene [Sm(Cp*)2(Тhf)2] (Cp* = η5-C5Me5) are studied. It is assumed that the reactions afford hetero-d/f-metal complexes. However, these complexes are not observed but the transfer of chalcogens from Ni to Sm and the formation of [(Sm(Cp*)2(Тhf))2(μ-S)] (III) and [(Sm(Cp*)2(Тhf))2(μ-Se)] (IV) occur. The second reaction products are [(LiPrNi)2(μ-η2:η2-S2)] (V) in the case of sulfur and [(LiPrNiI)2(μ-η6:η6-C7H8)2] (VI) in the case of selenium. All reaction products have been described previously, but compounds III and V are isolated as new crystalline phase, the structures of which are determined by X-ray diffraction analysis (CIF files CCDC nos. 1559045 (V) and 1559046 (III)).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Brennan, J., in The Rare Earth Elements: Fundamentals and Applications, Atwood, J., Ed., 2012, p.215.

  2. Li, H.X., Zhu, Y.J., Cheng, M.L., et al., Coord. Chem. Rev., 2006, vol. 250, p. 2059.

    Article  CAS  Google Scholar 

  3. Nief, F., Coord. Chem. Rev., 1998, vols. 178-180, p.13.

    Article  CAS  Google Scholar 

  4. Moore, B.F., Kumar, G.A., Tan, M., et al, J. Am. Chem. Soc., 2011, vol. 132, p.373.

    Article  Google Scholar 

  5. Kornienko, A., Moore, B.F., Kumar, G.A., et al., Inorg. Chem., 2011, vol. 50, p. 9184.

    Article  CAS  Google Scholar 

  6. Banerjee, S., Kumar, A., Emge, T., et al., Chem. Mater., 2008, vol. 20, p. 4367.

    Article  CAS  Google Scholar 

  7. Kumar, G.A., Riman, R.E., Diaz Torres, L.A., et al., Chem. Mater., 2007, vol. 19, p. 2937.

    Article  CAS  Google Scholar 

  8. Layfield, R.A., Organometallics, 2014, vol. 33, p. 1084.

    Article  CAS  Google Scholar 

  9. Pugh, T., Vieru, V., Chibotaru, L., and Layfield, R.A., Chem. Sci., 2016, vol. 7, p. 2128.

    Article  CAS  Google Scholar 

  10. Konchenko, S.N., Scheer, M., Roesky, P.W., et al., Angew. Chem., Int. Ed. Engl., 2016, vol. 55, p. 1557.

    Article  Google Scholar 

  11. Arleth, N., Gamer, M.T., Köppe, R., Roesky, P.W., et al., Chem. Sci., 2015, vol. 6, p. 7179.

    Article  CAS  Google Scholar 

  12. Li, T., Wiecko, J., Konchenko, S.N., et al., Angew. Chem., Int. Ed. Engl., 2011, vol. 50, p. 9491.

    Article  CAS  Google Scholar 

  13. Li, T., Gamer, M.T., Konchenko, S.N., et al., Inorg. Chem., 2013, vol. 54, p. 14231.

    Article  Google Scholar 

  14. Li, T., Gamer, M.T., Konchenko, S.N., et al., Chem. Commun., 2013, vol. 49, p. 2183.

    Article  CAS  Google Scholar 

  15. Konchenko, S.N., Sanden, T., Pushkarevsky, N.A., et al., Chem.-Eur. J., 2010, vol. 16, p. 14278.

    Article  CAS  Google Scholar 

  16. Yao, S., Milsmann, C., Bill, E., et al., J. Am. Chem. Soc., 2008, vol. 130, p. 13536.

    Article  CAS  Google Scholar 

  17. Yao, S., Xiong, Y., and Zhang, X., Angew. Chem., Int. Ed. Engl., 2009, vol. 48, p. 4551.

    Article  CAS  Google Scholar 

  18. Evans, W.J., Bloom, I., Hunter, W.E., and Atwood, J.L., J. Am. Chem. Soc., 1981, vol. 103, p. 6507.

    Article  CAS  Google Scholar 

  19. APEX2 (version 2.0), SAINT (version 8.18c), SADABS (version 2.11), Madison (WI, USA): Bruker AXS Inc., 2000–2012.

  20. Sheldrick, G.M., Acta Crystalllogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p.112.

    Article  CAS  Google Scholar 

  21. Sheldrick, G.M., Acta Crystalllogr., Sect. C: Struct. Chem., 2015, vol. 71, p.3.

    Article  Google Scholar 

  22. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., et al., Appl. Crystalllogr., 2009, vol. 42, p.339.

    Article  CAS  Google Scholar 

  23. Evans, W.J., Rabe, G.W., Ziller, J.W., and Doedens, R.J., Inorg. Chem., 1994, vol. 33, p. 2719.

    Article  CAS  Google Scholar 

  24. Bai, G., Wei, P., and Stephan, D.W., Organometallics, 2005, vol. 24, p. 5901.

    Article  CAS  Google Scholar 

  25. Maria, L., Soares, M., Santos, I.C., et al., Dalton Trans., 2016, vol. 45, p. 3778.

    Article  CAS  Google Scholar 

  26. Fieser, M.E., Johnson, C.W., Bates, J.E., et al., Organometallics, 2015, vol. 34, p. 4387.

    Article  CAS  Google Scholar 

  27. Turcitu, D., Nief, F., and Ricard, L., Chem.-Eur. J., 2003, vol. 9, p. 4916.

    Article  CAS  Google Scholar 

  28. Janiak, C., Dalton Trans., 2000, p. 3885.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    M. Yu. Afonin, T. S. Sukhikh, A. Yu. Konokhova & S. N. Konchenko

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    T. S. Sukhikh, A. Yu. Konokhova & S. N. Konchenko

Authors
  1. M. Yu. Afonin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. S. Sukhikh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Yu. Konokhova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. N. Konchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. Yu. Afonin.

Additional information

Original Russian Text © M.Yu. Afonin, T.S. Sukhikh, A.Yu. Konokhova, S.N. Konchenko, 2018, published in Koordinatsionnaya Khimiya, 2018, Vol. 44, No. 1, pp. 58–64.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Afonin, M.Y., Sukhikh, T.S., Konokhova, A.Y. et al. Reactions of Chalcogenide β-Diiminate Nickel Complexes with Samarium Bis(pentamethylcyclopentadienide). Russ J Coord Chem 44, 147–154 (2018). https://doi.org/10.1134/S107032841802001X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107032841802001X

Keywords

Search

Navigation