Skip to main content
SpringerLink
Log in

Switching of the exchange interaction character in the binuclear copper(II) complexes based on the hetaryl derivatives of 1,3-diaminopropanol-2

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The binuclear copper(II) complex with bis-azomethine, viz., the product of condensation of 1,3-diaminopropanol-2 with 4-hydroxy-3-formylcoumarin (H3L), of the composition [Cu2L(μ2-CH3COO)] (I) is synthesized and studied. Complex I is characterized by the exchange interaction of the antiferromagnetic type (2J =–112 cm–1), which is switched to the ferromagnetic one (2J = +106 cm–1) after the recrystallization of the complex from dimethyl sulfoxide (DMSO) to form solvate [Cu2L(μ2-CH3COO)(μ2-DMSO)] · 0.5DMSO (II). The structure of solvate II is studied by X-ray diffraction analysis (CIF file CCDC no. 982198). The difference in the exchange character is explained by the stabilization by the μ2-coordinated DMSO molecule of a distorted (roof-shaped type) conformation of the polydentate ligand and the complex as a whole, unlike the symmetric conformation characteristic of the nonsolvated complex. The data obtained are compared with those on similar compounds synthesized earlier and with the quantum chemical modeling results for the exchange interaction in the framework of the DFT-BS approximation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kogan, V.A., Lukov, V.V., and Shcherbakov, I.N., Russ. J. Coord. Chem., 2010, vol. 36, no. 6, p. 401.

    Article  CAS  Google Scholar 

  2. Levchenkov, S.I., Shcherbakov, I.N., Popov, L.D., et al., Russ. Chem. Bull., 2014, vol. 63, no. 3, p. 673.

    Article  CAS  Google Scholar 

  3. Wang, L.-L., Sun, Y.-M., Qi, Z.-N., and Liu, C.-B., J. Phys. Chem. A, 2008, vol. 112, no. 36, p. 8418.

    Article  CAS  Google Scholar 

  4. Vigato, P.A. and Tamburini, S., Coord. Chem. Rev., 2008, vol. 252, nos. 18–20, p. 1871.

    Article  CAS  Google Scholar 

  5. Vigato, P.A., Peruzzo, V., and Tamburini, S., Coord. Chem. Rev., 2012, vol. 256, nos. 11–12, p. 953.

    Article  CAS  Google Scholar 

  6. Lukov, V.V., Shcherbakov, I.N., Levchenkov, S.I., et al., Russ. J. Coord. Chem., 2017, vol. 43, no. 1, p. 1.

    Article  CAS  Google Scholar 

  7. Tupolova, Y., Popov, L., Levchenkov, S., et al., Russ. J. Coord. Chem., 2011, vol. 37, no. 7, p. 552.

    Article  CAS  Google Scholar 

  8. Lee, C.-J., Cheng, S.-C., Lin, H.-H., and Wei, H.-H., Inorg. Chem. Commun., 2005, vol. 8, no. 3, p. 235.

    Article  CAS  Google Scholar 

  9. Kawata, T., Ohba, S., Nishida, Y., and Tokii, T., Acta Crystallogr., Sect. C: Cryst. Struct. Comm., 1993, vol. 49, no. 12, p. 2070.

    Article  Google Scholar 

  10. Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N., et al., Inorg. Chem. Commun., 2012, vol. 17, p. 1.

    Article  CAS  Google Scholar 

  11. Shcherbakov, I.N., Levchenkov, S.I., Tupolova, Y.P., et al., Eur. J. Inorg. Chem., 2013, vol. 2013, no. 28, p. 5033.

    CAS  Google Scholar 

  12. Levchenkov, S.I., Shcherbakov, I.N., Popov, L.D., et al., Russ. J. Coord. Chem., 2014, vol. 40, no. 8, p. 523.

    Article  CAS  Google Scholar 

  13. Shcherbakov, I.N., Levchenkov, S.I., Popov, L.D., et al., Russ. J. Coord. Chem., 2015, vol. 41, no. 2, p. 69.

    Article  CAS  Google Scholar 

  14. Bleaney, B. and Bowers, K.D., Proc. R. Soc. London A, 1952, vol. 214, no. 1119, p. 451.

    Article  CAS  Google Scholar 

  15. Carlin, R.L., Magnetochemistry, Berlin Heidelberg: Springer and GmbH & Co. K, 1986.

    Book  Google Scholar 

  16. Kahn, O., Molecular Magnetism, New York: VCH, 1993.

    Google Scholar 

  17. SMART and SAINT. Release 5.0. Area Detector Control and Integration Software, Madison (WI, USA): Bruker AXS, Analytical X-ray Instruments, 1998.

    Google Scholar 

  18. Sheldrick, G.M., SADABS. A Program for Exploiting the Redundancy of Area-Detector X-ray Data, Göttingen: Univ. of Göttingen, 1999.

    Google Scholar 

  19. Sheldrick, G., Acta Crystallogr. Sect. A: Found. Crystallogr., 2008, vol. 64, no. 1, p. 112.

    Article  CAS  Google Scholar 

  20. Spek, A., J. Appl. Crystallogr., 2003, vol. 36, no. 1, p. 7.

    Article  CAS  Google Scholar 

  21. Chernyshov, A.A., Veligzhanin, A.A., and Zubavichus, Y.V., Nucl. Instrum. Methods Phys. Res., A, 2009, vol. 603, nos. 1–2, p. 95.

    Article  CAS  Google Scholar 

  22. Kochubei, D.I., Babanov, Yu.A., Zamaraev, K.I. Rentgenospektral’nyi metod izucheniya struktury amorfnykh tel: EXAFS-spektroskopiya (X-ray Spectral Metod for Investigation of Amorphous Solids: EXAFS Spektroscopy) Novosibirsk: Nauka, 1988.

    Google Scholar 

  23. Newville, M., J. Synchrotron Radiat., 2001, vol. 8, no. 2, p. 322.

    Article  CAS  Google Scholar 

  24. Zabinsky, S.I., Rehr, J.J., Ankudinov, A., et al., Phys. Rev. B, 1995, vol. 52, no. 4, p. 2995.

    Article  CAS  Google Scholar 

  25. Groom, C.R., Bruno, I.J., Lightfoot, M.P., and Ward, S.C., Acta Crystallogr., Sect. B: Struct. Sci., Cryst. Eng. Mater., 2016, vol. 72, no. 2, p. 177.

    Article  Google Scholar 

  26. Frisch, M.J., Trucks, G.W., Schlegel, H.B., et al., Gaussian 03. Revision E.1, 2003.

    Google Scholar 

  27. Becke, A.D., J. Chem. Phys., 1993, vol. 98, no. 7, p. 5648.

    Article  CAS  Google Scholar 

  28. Malrieu, J.P., Caballol, R., Calzado, C.J., et al., Chem. Rev., 2013, vol. 114, no. 1, p. 429.

    Article  Google Scholar 

  29. Comba, P. and Kerscher, M., Coord. Chem. Rev., 2009, vol. 253, nos. 5–6, p. 564.

    Article  CAS  Google Scholar 

  30. Ruiz, E., Exchange Coupling in Di-and Polynuclear Complexes, Comprehensive Inorganic Chemistry II, 2nd ed., 2013, vol. 9, p. 501.

    CAS  Google Scholar 

  31. Levchenkov, S.I., Shcherbakov, I.N., Popov, L.D., et al., Inorg. Chim. Acta, 2013, vol. 405, p. 169.

    Article  CAS  Google Scholar 

  32. Yamaguchi, K., Takahara, Y., Fueno, T., and Houk, K.N., Theor. Chim. Acta, 1988, vol. 73, no. 5, p. 337.

    Article  CAS  Google Scholar 

  33. Nishida, Y. and Kida, S., Inorg. Chem., 1988, vol. 27, no. 3, p. 447.

    Article  CAS  Google Scholar 

  34. Elmali, A., Zeyrek, C.T., and Elerman, Y., J. Mol. Struct., 2004, vol. 693, nos. 1–3, p. 225.

    Article  CAS  Google Scholar 

  35. Kogan V.A., Lukov V.V., Novotortsev V.M., et al., Izv. Ross. Akad. Nauk, Ser. Khim., 2005, vol. 4, no. 3, p. 592.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Southern Federal University, Rostov-on-Don, Russia

    I. N. Shcherbakov, L. D. Popov, S. I. Levchenkov, Yu. P. Tupolova & V. V. Lukov

  2. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    S. I. Levchenkov

  3. Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russia

    V. G. Vlasenko

  4. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    G. G. Aleksandrov

Authors
  1. I. N. Shcherbakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. D. Popov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. I. Levchenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. G. Vlasenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. G. Aleksandrov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Yu. P. Tupolova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. V. Lukov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. N. Shcherbakov.

Additional information

† Deceased.

Original Russian Text © I.N. Shcherbakov, L.D. Popov, S.I. Levchenkov, V.G. Vlasenko, G.G. Aleksandrov, Yu.P. Tupolova, V.V. Lukov, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 11, pp. 659–667.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shcherbakov, I.N., Popov, L.D., Levchenkov, S.I. et al. Switching of the exchange interaction character in the binuclear copper(II) complexes based on the hetaryl derivatives of 1,3-diaminopropanol-2. Russ J Coord Chem 43, 727–735 (2017). https://doi.org/10.1134/S1070328417110082

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328417110082

Keywords

Search

Navigation