Russian Journal of Coordination Chemistry

, Volume 43, Issue 10, pp 630–634 | Cite as

Structure of the Planar Acetate-Bridged Binuclear Copper(II) Complex Based on 1,3-Bis(3-Formyl-5-tert-Butylsalicylidenimino)propanol-2

  • S. I. Levchenkov
  • L. D. Popov
  • Yu. P. Tupolova
  • A. N. Morozov
  • E. A. Raspopova
  • Z. A. Starikova
  • I. N. Shcherbakov
Article
  • 34 Downloads

Abstract

The X-ray diffraction and magnetochemical studies of the acetate-bridged binuclear copper(II) complex with 1,3-bis(3-formyl-5-tert-butylsalicylidenimino)propanol-2 with a nearly planar structure of the exchange fragment are carried out (СIF file CCDC 940849). The assumption that the magnetic exchange in the complexes with the anticomplementary carboxylate exogenic bridges 1,3-O,O' is determined only by the structural factors and the bridging coordination of the solvent molecule changes the type of the exchange interaction between the copper(II) ions is proved to be true.

Keywords

binuclear copper(II) complexes magnetochemistry exchange interaction X-ray diffraction analysis 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Tupolova, Yu.P., Popov, L.D., Levchenkov, S.I., et al., Russ. J. Coord. Chem., 2011, vol. 37, no. 7, p. 552.CrossRefGoogle Scholar
  2. 2.
    Shcherbakov, I.N., Levchenkov, S.I., Tupolova, Yu.P., et al., Eur. J. Inorg. Chem., 2013, vol. 2013, no. 28, p. 5033.Google Scholar
  3. 3.
    Levchenkov, S.I., Shcherbakov, I.N., Popov, L.D., et al., Izv. Ross. Akad. Nauk., Ser. Khim., 2014, no. 3, p. 673.Google Scholar
  4. 4.
    Levchenkov, S.I., Shcherbakov, I.N., Popov, L.D., et al., Russ. J. Coord. Chem., 2014, vol. 40, no. 8, p. 523.CrossRefGoogle Scholar
  5. 5.
    SMART and SAINT. Release 5.0. Area Detector Control and Integration Software, Madison: Bruker AXS, Analytical X-ray Instruments, 1998.Google Scholar
  6. 6.
    Sheldrick, G.M., SADABS. A Program for Exploiting the Redundancy of Area-detector X-ray Data, Göttingen: Univ. of Göttingen, 1999.Google Scholar
  7. 7.
    Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, no. 1, p. 112.CrossRefGoogle Scholar
  8. 8.
    Spek, A.L., J. Appl. Crystallogr., 2003, vol. 36, p. 7.CrossRefGoogle Scholar
  9. 9.
    Kawata, T., Ohba, S., Nishida, Y., and Tokii, T., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1993, vol. 49, no. 12, p. 2070.CrossRefGoogle Scholar
  10. 10.
    Kogan, V.A., Lukov, V.V., and Shcherbakov, I.N., Russ. J. Coord. Chem., 2010, vol. 36, no. 6, p. 403.CrossRefGoogle Scholar
  11. 11.
    Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N., et al., Inorg. Chem. Commun., 2012, vol. 17, p. 1.CrossRefGoogle Scholar
  12. 12.
    Mukherjee, A., Saha, M.K., Rudra, I., et al., Inorg. Chim. Acta, 2004, vol. 357, no. 4, p. 1077.CrossRefGoogle Scholar
  13. 13.
    Kogan, V.A., Lukov, V.V., Novotortsev, V.M., et al., Izv. Ros. Akad. Nauk., Ser. Khim., 2005, vol. 54, no. 3, p. 592.Google Scholar
  14. 14.
    Kahn, O., Molecular Magnetism, New York: VCH, 1993.Google Scholar
  15. 15.
    Lukov, V.V., Shcherbakov, I.N., Levchenkov, S.I., et al., Russ. J. Coord. Chem., 2017, vol. 43, no. 1, p. 1.CrossRefGoogle Scholar
  16. 16.
    Nishida, Y. and Kida, S., Inorg. Chem., 1988, vol. 27, no. 3, p. 447.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • S. I. Levchenkov
    • 1
    • 2
  • L. D. Popov
    • 2
  • Yu. P. Tupolova
    • 2
  • A. N. Morozov
    • 2
  • E. A. Raspopova
    • 2
  • Z. A. Starikova
    • 3
  • I. N. Shcherbakov
    • 2
  1. 1.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  2. 2.Southern Federal UniversityRostov-on-DonRussia
  3. 3.Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia

Personalised recommendations