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Zn-containing double complex salts formed by Keggin type polyoxotungstates: Synthesis and crystal structure

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Abstract

Novel double complex salts, [Zn(DMF)6]2[SiW12O40] · 2H2O (I) and [Zn(H2O)2(DMF)4][Zn(DMF)6]2[PW12O40]2 · 6DMF (II) (DMF = N,N-dimethylformamide), were prepared by the reaction of Zn2+ and heteropoly acids Hx[EW12O40] · xH2O (E = P, X = 3, E = Si, X = 4) in DMF. Compounds I and II were studied by X-ray diffraction (СIF files CCDC nos. 1497570 (I) and 1497571 (II)) and IR spectroscopy.

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Authors and Affiliations

  1. Novosibirsk State University, Novosibirsk, 630090, Russia

    L. I. Udalova, S. A. Adonin, P. A. Abramov & I. V. Korolkov

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    S. A. Adonin, P. A. Abramov, I. V. Korolkov & M. N. Sokolov

  3. Butlerov Institute of Chemistry, Kazan (Volga Region) Federal University, Kazan, 420008, Russia

    M. N. Sokolov

Authors
  1. L. I. Udalova
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  2. S. A. Adonin
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  3. P. A. Abramov
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  4. I. V. Korolkov
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  5. M. N. Sokolov
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Correspondence to S. A. Adonin.

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Original Russian Text © L.I. Udalova, S.A. Adonin, P.A. Abramov, I.V. Korolkov, M.N. Sokolov, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 6, pp. 352–356.

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Udalova, L.I., Adonin, S.A., Abramov, P.A. et al. Zn-containing double complex salts formed by Keggin type polyoxotungstates: Synthesis and crystal structure. Russ J Coord Chem 43, 368–372 (2017). https://doi.org/10.1134/S1070328417050086

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  • DOI: https://doi.org/10.1134/S1070328417050086

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