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Synthesis, characterization, and biological activity of Cd(II) and Mn(II) coordination polymers based on pyridine-2,6-dicarboxylic acid

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Abstract

The coordination polymers (CPs) {[Cd(Pydc)(H2O)3] · PydcH2} (I) and [Mn(Pydc)(H2O)3] · PydcH2} (II) were obtained by the reaction of CdSO4 · 5H2O or MnCl2 · 4H2O with pyridine-2,6-dicarboxylic acid (PydcH2). The structures of the CPs I and II were characterized by IR, UV-Vis, TGA, and X-ray single crystal analysis (CIF files CCDC nos. 1417757 (I), 1417758 (II)). The network structures of I and II are constructed by an infinite number of discrete binuclear molecules and free PydcH2. The structures of the CPs I and II connected by the extensive H-bonds and π–π stacking, forming a 3D-network. The CPs I and II were screened to test their antimicrobial activities against different species of bacteria and fungi.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt

    S. E. H. Etaiw, M. M. El-Bendary & H. Abdelazim

  2. Chemistry Department, Faculty of Science, University of Jeddah, Jeddah, Saudi Arabia

    M. M. El-Bendary

Authors
  1. S. E. H. Etaiw
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  2. M. M. El-Bendary
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  3. H. Abdelazim
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Correspondence to M. M. El-Bendary.

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Etaiw, S.E.H., El-Bendary, M.M. & Abdelazim, H. Synthesis, characterization, and biological activity of Cd(II) and Mn(II) coordination polymers based on pyridine-2,6-dicarboxylic acid. Russ J Coord Chem 43, 320–330 (2017). https://doi.org/10.1134/S1070328417050013

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