Abstract
The reactions of pentaphenylantimony with oximes or triphenylantimony dioximates in toluene afford tetraphenylantimony oximates Ph4SbON=CHR (R = C6H4Br-2 (I), C6H4NO2-2 (II), and C4H3S-2 (III)). Triphenylantimony dioximates are synthesized by oxidative addition from triphenylantimony and oxime in diethyl ether in the presence of tert-butyl hydroperoxide. According to the X-ray diffraction data (CIF files CCDC no. 1055414 (I), 1055634 (II), and 1061727 (III)), the coordination mode of the antimony atoms in the molecules of compounds I–III is a distorted trigonal bipyramid with the oxygen atom of the oximate ligand in the axial position. The structural organization of the crystals is caused by weak hydrogen bonds.
Similar content being viewed by others
References
Bajpai, K. and Srivastava, R.C., Synth. Inorg. Met. Org. Chem., 1981, vol. 11, no. 1, p. 7.
Tiekink, E.R.T., Crit. Rev. Oncol./Hematol., 2002, vol. 42, p. 217.
Ozturk, I.I., Banti, C.N., Manos, M.J., et al., J. Inorg. Biochem., 2012, vol. 109, p. 57.
Ali, M.I., Rauf, M.K., Badshah, A., et al., Dalton Trans., 2013, vol. 42, p. 16733.
Yu, L., Ma, Y.-Q., Wang, G.-C., and Li, J.-S., Heteroatom. Chem., 2004, vol. 15, p. 32.
Yin, H., Quan, L., and Li, L., Inorg. Chem. Commun., 2008, vol. 11, no. 10, p. 1121.
Domasevich, K.V., Chernega, A.N., Lindeman, S.V., et al., Zh. Inorg. Khim., 1995, vol. 40, no. 3, p. 426.
Sharutin, V.V., Sharutina, O.K., Molokova, O.V., et al., Russ. J. Gen. Chem., 2000, vol. 70, no. 12, p. 1872.
Sharutin, V.V., Sharutina, O.K., Molokova, O.V., et al., Russ. J. Gen. Chem., 2001, vol. 71, no. 8, p. 1243.
Sharutin, V.V., Sharutina, O.K., Molokova, O.V., et al., Russ. J. Coord. Chem., 2002, vol. 28, no. 8, p. 544.
SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System, Madison: Bruker AXS Inc., 1998.
SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data, Madison: Bruker AXS Inc., 1998.
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., et al., J. Appl. Crystallogr., 2009, vol. 42, p. 339.
Sharutin V.V. and Senchurin, V.S. Imennye reaktsii v khimii elementoorganicheskikh soedinenii (Name Reactions in Heteroorganic Chemistry), Chelyabinsk: Izdatel’skii tsentr YuUrGU, 2011.
Batsanov, S.S., Zh. Neorg. Khim., 1991, vol. 36, no. 12, p. 3015.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.V. Sharutin, O.K. Sharutina, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 4, pp. 244–249.
Rights and permissions
About this article
Cite this article
Sharutin, V.V., Sharutina, O.K. Syntheses and structures of tetraphenylantimony oximates: Ph4SbON=CHR (R = C6H4Br-2, C6H4NO2-2, C4H3S). Russ J Coord Chem 43, 232–237 (2017). https://doi.org/10.1134/S1070328417040054
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070328417040054