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Nanostructured catalysts for direct electrooxidation of dimethyl ether based on Bi- and trimetallic Pt–Ru and Pt–Ru–Pd alloys prepared from coordination compounds

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Abstract

Bi- and trimetallic platinum–ruthenium and platinum–ruthenium–palladium catalysts with specified atomic ratios Pt: Ru = 1: 1 and Pt: Ru: Pd = 1: 1: 0.1, respectively, were synthesized from the coordination compounds of the metals deposited on highly dispersed carbon black. The catalysts were characterized by powder X-ray diffraction, electron dispersive analysis, and transmission electron microscopy. According to voltammetry data, the highest activity in the dimethyl ether (DME) electrooxidation is exhibited by the catalyst Pt0.43Ru0.47Pd0.1/C; hence, it may be considered as a promising anode material for direct DME fuel cells.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 117071, Russia

    V. A. Grinberg, N. A. Maiorova, V. V. Emets, A. A. Shiryaev, V. V. Vysotskii, V. K. Gerasimov, V. V. Matveev, E. A. Nizhnikovskii & V. N. Andreev

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 117907, Russia

    A. A. Pasynskii

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  1. V. A. Grinberg
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  2. N. A. Maiorova
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  3. A. A. Pasynskii
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  4. V. V. Emets
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  5. A. A. Shiryaev
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  6. V. V. Vysotskii
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  7. V. K. Gerasimov
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  8. V. V. Matveev
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  9. E. A. Nizhnikovskii
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  10. V. N. Andreev
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Correspondence to V. A. Grinberg or A. A. Pasynskii.

Additional information

Original Russian Text © V.A. Grinberg, N.A. Maiorova, A.A. Pasynskii, V.V. Emets, A.A. Shiryaev, V.V. Vysotskii, V.K. Gerasimov, V.V. Matveev, E.A. Nizhnikovskii, V.N. Andreev, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 4, pp. 204–211.

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Grinberg, V.A., Maiorova, N.A., Pasynskii, A.A. et al. Nanostructured catalysts for direct electrooxidation of dimethyl ether based on Bi- and trimetallic Pt–Ru and Pt–Ru–Pd alloys prepared from coordination compounds. Russ J Coord Chem 43, 206–212 (2017). https://doi.org/10.1134/S1070328417040017

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  • DOI: https://doi.org/10.1134/S1070328417040017

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