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Electrochemical synthesis, properties, and structure of copper, nickel, and cobalt complexes of tridentate tosylamino-functionalized mercaptopyrazole Schiff base

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Abstract

Copper, nickel, and cobalt complexes of the N,N,S-tridentate tosylamino-functionalized mercaptopyrazole Schiff base were obtained by an electrochemical method. The structure and composition of the metal chelates were characterized by C, H, N elemental analysis data and IR and 1H NMR spectroscopy. More data on the structures of the complexes were obtained by magnetochemical and X-ray absorption spectroscopy measurements. The mononuclear structure of the copper(II) complex was confirmed by X-ray diffraction (CIF file CCDC no. 1473320).

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Correspondence to D. A. Garnovskii.

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Original Russian Text © D.A. Garnovskii, S.I. Levchenkov, G.G. Aleksandrov, V.G. Vlasenko, Ya.V. Zubavichus, A.I. Uraev, A.S. Burlov, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 3, pp. 147–155.

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Garnovskii, D.A., Levchenkov, S.I., Aleksandrov, G.G. et al. Electrochemical synthesis, properties, and structure of copper, nickel, and cobalt complexes of tridentate tosylamino-functionalized mercaptopyrazole Schiff base. Russ J Coord Chem 43, 156–163 (2017). https://doi.org/10.1134/S1070328417030010

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  • DOI: https://doi.org/10.1134/S1070328417030010

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