Russian Journal of Coordination Chemistry

, Volume 43, Issue 3, pp 156–163 | Cite as

Electrochemical synthesis, properties, and structure of copper, nickel, and cobalt complexes of tridentate tosylamino-functionalized mercaptopyrazole Schiff base

  • D. A. Garnovskii
  • S. I. Levchenkov
  • G. G. Aleksandrov
  • V. G. Vlasenko
  • Ya. V. Zubavichus
  • A. I. Uraev
  • A. S. Burlov
Article

Abstract

Copper, nickel, and cobalt complexes of the N,N,S-tridentate tosylamino-functionalized mercaptopyrazole Schiff base were obtained by an electrochemical method. The structure and composition of the metal chelates were characterized by C, H, N elemental analysis data and IR and 1H NMR spectroscopy. More data on the structures of the complexes were obtained by magnetochemical and X-ray absorption spectroscopy measurements. The mononuclear structure of the copper(II) complex was confirmed by X-ray diffraction (CIF file CCDC no. 1473320).

Keywords

electrochemical synthesis tridentate Schiff base metal chelates binuclear copper complex X-ray diffraction 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • D. A. Garnovskii
    • 1
  • S. I. Levchenkov
    • 1
  • G. G. Aleksandrov
    • 2
  • V. G. Vlasenko
    • 3
  • Ya. V. Zubavichus
    • 4
  • A. I. Uraev
    • 5
  • A. S. Burlov
    • 5
  1. 1.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  2. 2.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  3. 3.Research Institute of PhysicsSouthern Federal UniversityRostov-on-DonRussia
  4. 4.National Research Center “Kurchatov Institute”MoscowRussia
  5. 5.Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-DonRussia

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