Skip to main content
SpringerLink
Log in

CpFe(CO)2TePh as a ligand for organometallic dihalides Fe(CO)4I2, (p-Cymene)RuI2, and Me5C5RhI2: Synthesis and molecular structures

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

CpFe(CO)2TePh (I) can substitute one carbonyl group in Fe(CO)4I2 providing Fe(CO)3I2(μ-TePh)Fe(CO)2Cp (II) or play role of ligand to monomeric fragments [(p-Cymene)RuI2] and [Сp*RhI2] (p-Cymene = (η6-1-isopropyl-4-methylbenzene); Сp* = η5-pentamethylcyclopentadienyl) provides the complexes (p-Cymene)RuI2(μ-TePh)Fe(CO)2Cp (III) and Cp*RhCl2(μ-TePh)Fe(CO)2Cp (IV), respectively. The single-crystal X-ray diffraction of complexes II–IV (CIF files CCDC nos. 1038124 (II), 1038127 (III), 1038125 (IV)) revealed the shortening of М–Те bonds and the presence of intramolecular I…Te contacts.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Pasynskii, A.A., Torubaev, Yu.V., Pavlova, A.V., et al., Russ. J. Coord. Chem., 2014, vol. 40, no. 9, p. 611.

    Article  CAS  Google Scholar 

  2. Pasynskii, A.A., Torubaev, Y.V., Pavlova, A.V., et al., J. Clust. Sci., 2015, vol. 26, no. 1, p. 247.

    Article  CAS  Google Scholar 

  3. Nakagawa, T., Seino, H., Nagao, Sh., and Mizobe, Ya., Angew. Chem. Int. Ed., 2006, vol. 45, p. 7758.

    Article  CAS  Google Scholar 

  4. Nakagawa, T., Seino, H., and Mizobe, Ya., Organometallics, 2010, vol. 695, p. 13.

    Google Scholar 

  5. Liaw, W.-F., Chuang, C.-Yu., Lee, W.-Z., et al., Inorg. Chem., 1996, vol. 35, p. 2530.

    Article  CAS  Google Scholar 

  6. Hsieh, C.-K., Lo, F.-C., Lee, G.-H., et al., J. Chin. Chem. Soc. (Taipei), 2000, vol. 47, p. 103.

    Article  CAS  Google Scholar 

  7. Pasynskii, A.A., Skabitskiy, I.V., Shapovalov, S.S., et al., Russ. Chem. Bull., Int. Ed., 2007, vol. 56, p. 1731.

    Article  CAS  Google Scholar 

  8. Torubaev, Yu.V., Pasynskii, A.A., and Skabitskii, I.V., Russ. J. Coord. Chem., 2009, vol. 35, no. 5, p. 341.

    Article  CAS  Google Scholar 

  9. Shapovalov, S.S., Pasynskii, A.A., Skabitskiy, I.V., et al., Russ. J. Coord. Chem., 2013, vol. 39, no. 12, p. 716.

    Article  Google Scholar 

  10. Pasynskii, A.A., Shapovalov, S.S., Torubaev, Yu.V., et al., Russ. J. Coord. Chem., 2014, vol. 40, no. 10, p. 579.

    Article  Google Scholar 

  11. Hieber, W. and Bader, G., Ber. Dtsch. Chem. Ges., 1928, vol. 61, p. 1717.

    Article  Google Scholar 

  12. Bennett, M.A. and Smith, A.K., J. Chem. Soc., Dalton Trans., 1974, p. 233.

    Google Scholar 

  13. White, C., Yates, A., Maitlis, P.M., and Heinekey, D.M., Inorg. Synth., 1992, vol. 29, p. 228.

    Article  CAS  Google Scholar 

  14. Sheldrick, G.M., SHELXTL-97, Version 5.50, Madison Bruker AXS Inc., 1997.

    Google Scholar 

  15. Spek, A.L., Acta Crystallogr., Sect. D: Biol. Crystallogr., 2009, vol. 65, p. 148.

    Article  CAS  Google Scholar 

  16. Cordero, B., Gr'omez, V., Platero-Prats, A.E., et al., Dalton Trans., 2008, p. 2832.

    Google Scholar 

  17. Pasynskii, A.A., Russ. J. Coord. Chem., 2011, vol. 37, no. 11, p. 801.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. A. Pasynskii, I. V. Skabitskiy, Yu. V. Torubaev, A. V. Pavlova, S. S. Shapovalov & S. G. Sakharov

  2. Higher Chemical College of the Russian Academy of Sciences, Miusskaya pl. 9, Moscow, 125047, Russia

    O. G. Tikhonova

Authors
  1. A. A. Pasynskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. V. Skabitskiy
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. V. Torubaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Pavlova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. S. Shapovalov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. O. G. Tikhonova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. S. G. Sakharov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Pasynskii.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pasynskii, A.A., Skabitskiy, I.V., Torubaev, Y.V. et al. CpFe(CO)2TePh as a ligand for organometallic dihalides Fe(CO)4I2, (p-Cymene)RuI2, and Me5C5RhI2: Synthesis and molecular structures. Russ J Coord Chem 43, 44–49 (2017). https://doi.org/10.1134/S1070328417010067

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328417010067

Keywords

Search

Navigation