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Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II)

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Abstract

The structure of the dimeric complex [Co2(BuOH)4(Detba)4] (I), where НDetba is 1,3-diethyl-2-thiobarbituric acid, and BuOH is butanol-1, is determined (CIF file CCDC 1475273), and its IR spectrum is studied. The crystals are monoclinic: a = 10.7185(5), b = 21.985(1), c = 12.7235(7) Å, β = 92.196(2)°, V = 2996.1(3) Å3, space group P21/c, Z = 2. The Co2+ ions in compound I are joined in pairs by bridging ligands μ2-Detba–−O,O'. In addition, each of them is linked through the O atoms to one terminal Detba–ion and two BuOH molecules to form a trigonal bipyramid СоО5. Hydrogen bonds O–H···O formed by BuOH and Detba– join the binuclear complexes into an infinite chain. The data of IR spectroscopy are consistent with the results of X-ray diffraction analysis.

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Authors and Affiliations

  1. Siberian Federal University, Krasnoyarsk, Russia

    N. N. Golovnev & M. K. Lesnikov

  2. Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russia

    M. S. Molokeev

  3. Far East State Transport University, Khabarovsk, 680021, Russia

    M. S. Molokeev

  4. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    A. I. Smolentsev

  5. Novosibirsk National Research State University, Novosibirsk, 630090, Russia

    A. I. Smolentsev

Authors
  1. N. N. Golovnev
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  2. M. S. Molokeev
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  3. A. I. Smolentsev
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  4. M. K. Lesnikov
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Correspondence to N. N. Golovnev.

Additional information

Original Russian Text © N.N. Golovnev, M.S. Molokeev, A.I. Smolentsev, M.K. Lesnikov, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 2, pp. 81–84.

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Golovnev, N.N., Molokeev, M.S., Smolentsev, A.I. et al. Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II). Russ J Coord Chem 43, 82–85 (2017). https://doi.org/10.1134/S1070328417010031

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  • DOI: https://doi.org/10.1134/S1070328417010031

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