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Zinc(II) and cadmium(II) N,N'-Bis(2-N-Tosylaminobenzylidene) diaminodipropyliminates: Syntheses, structures, and photoluminescence properties

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Abstract

Chemical and electrochemical syntheses of the zinc(II) and cadmium(II) complexes with the tetradentate Schiff base (H2L), the condensation product of 2-N-tosylaminobenzaldehyde with diaminodipropylamine, are carried out. The structures, compositions, and properties of the synthesized metal complexes are studied by elemental analyses, IR spectroscopy, 1H NMR, UV spectroscopy, X-ray absorption spectroscopy, and quantum-chemical calculations. The structure of the cadmium(II) complex is determined by X-ray diffraction analysis (CIF file CCDC no. 1446393). The cadmium(II) and zinc(II) complexes exhibit luminescence in a CH2Cl2 solution in the blue spectral range (λPL = 425–428 nm) with the photoluminescence quantum yields ϕ = 0.20 and 0.75, respectively.

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Correspondence to A. S. Burlov.

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Original Russian Text © T.P. Lysakova, A.S. Burlov, V.G. Vlasenko, Yu.V. Koshchienko, G.G. Aleksandrov, S.I. Levchenkov, Ya.V. Zubavichus, A.S. Cheprasov, D.A. Garnovskii, A.V. Metelitsa, 2016, published in Koordinatsionnaya Khimiya, 2016, Vol. 42, No. 11, pp. 665–674.

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Lysakova, T.P., Burlov, A.S., Vlasenko, V.G. et al. Zinc(II) and cadmium(II) N,N'-Bis(2-N-Tosylaminobenzylidene) diaminodipropyliminates: Syntheses, structures, and photoluminescence properties. Russ J Coord Chem 42, 701–710 (2016). https://doi.org/10.1134/S1070328416110075

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  • DOI: https://doi.org/10.1134/S1070328416110075

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