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Mononuclear pivalates of metals of the first transition series

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Abstract

The synthesis and structures of mononuclear Ni(II), Co(II), Mn(II), and Cu(II) pivalates isolated as complex salts NBu4[M(Piv)3] ((NBu4)+ is tetrabutylammonium cation, Piv– is pivalate anion) and polynuclear complexes [Ni6(L)2(HL)2(Piv)6(HPiv)8], (NBu4)2[Co4(Piv)8(AcO)2(H2O)4], NBu4[Co2(Piv)5(H2O)2], and (NBu4)2[Cu4(Piv)8(AcO)2(H2O)2] (L2–, HL–, and AcO– is lactic acid dianion, lactic acid monoanion, and acetate anion, respectively) are discussed. The formation of the compounds is detected during the development of the synthesis of NBu4[M(Piv)3].

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Authors and Affiliations

  1. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    V. I. Ovcharenko, E. Yu. Fursova & G. V. Romanenko

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  1. V. I. Ovcharenko
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  2. E. Yu. Fursova
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  3. G. V. Romanenko
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Correspondence to V. I. Ovcharenko.

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Original Russian Text © V.I. Ovcharenko, E.Yu. Fursova, G.V. Romanenko, 2016, published in Koordinatsionnaya Khimiya, 2016, Vol. 42, No. 9, pp. 543–549.

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Ovcharenko, V.I., Fursova, E.Y. & Romanenko, G.V. Mononuclear pivalates of metals of the first transition series. Russ J Coord Chem 42, 584–590 (2016). https://doi.org/10.1134/S1070328416090049

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