Skip to main content
SpringerLink
Log in

Coordination silver polymer with the bridging anion of oxadiazolylacrylic acid: Synthesis, crystal structure, and luminescence properties

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Metal complex [AgL] (I) is synthesized by the reaction of AgNO3 with 3-(5-furyl-1,3,4-oxadiazol-2-yl)acrylic acid (HL, C9H6N2O4), and its crystal structure is determined (CIF file CCDC no. 1426528). The crystals are monoclinic, space group P21/n, a = 4.946(1), b = 20.084(1), c = 9.015(1) Å, β = 92.32(1)°, V = 894.482 Å3, ρcalcd = 2.442 g/cm3, Z = 4. In structure I, pairs of centrosymmetric silver atoms are bound by bidentate-bridging oxygen atoms of two anions L into dimeric blocks. The Ag–Ag distance in the dimer is 2.854(1) Å. The coordination sphere of Ag+ contains two oxygen atoms, one silver atom, and one nitrogen atom of the diazolyl fragment of the adjacent anion. The coordination polyhedron of Ag+ is a strongly distorted tetrahedron. The molecular packing of crystal I is built of infinite ribbons (AgL)n extended along the direction [001]. The photoluminescence spectrum of compound I contains intense bands about 550 nm corresponding to the green spectral range and less intense bands at 425 and 485 nm.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Pomogailo, A.D. and Dzhardimalieva, G.I., in Monomernye i polimernye karboksilaty metallov (Monomeric and Polymeric Metal Carboxylates), Moscow: Fizmatlit, 2009, p. 400.

    Google Scholar 

  2. Tokito, S., Noda, K., Tanaka, H., et al., Synth. Met., 2000, vols. 111–112, p. 393.

    Article  Google Scholar 

  3. Mehrotra, R.C. and Bohra, R., Metal Carboxylates, London: Academic, 1983, p. 396.

    Google Scholar 

  4. Kiskin, M.A. and Eremenko, I.L., Usp. Khim., 2006, vol. 75, p. 627.

    Article  Google Scholar 

  5. Dzhardimalieva, G.I. and Pomogailo, A.D., Usp. Khim., 2008, vol. 77, p. 270.

    Article  Google Scholar 

  6. Schubert, U., Chem. Mater., 2001, vol. 13, p. 3487.

    Article  CAS  Google Scholar 

  7. Metal Complexes and Metals in Macromolecules, Wohrle, D. and Pomogailo, A.D., Eds., Wiley VCH, 2003, p. 667.

  8. Supported Catalysts and Their Applications, Sherrington, D.C. and Kubert, A.P., Eds., Cambridge: Royal Soc. Chem., 2001. P. 250.

  9. Petukhova, M.V., Petrochenkova, N.V., Mirochnik, A.G., et al., Vysokomol. Soedin., Ser. B, 2002, vol. 44, p. 1267.

    CAS  Google Scholar 

  10. Ling, Q.D., Cai, Q.L., Kang, E.T., et al., J. Mater. Chem., 2004, vol. 14, p. 2741.

    Article  CAS  Google Scholar 

  11. Ling, Q., Yang, M., Wu, Z., et al., Polymer, 2001, vol. 42, p. 4605.

    Article  CAS  Google Scholar 

  12. Gao, M.Y., Yang, Y., Yang, B., et al., Chem. Commun., 1994, p. 2779.

    Google Scholar 

  13. Volkov, A.V., Moskvina, M.A., Karachevtsev, I.V., et al., Vysokomol. Soedin., Ser. A, 1998, vol. 40, p. 45.

    CAS  Google Scholar 

  14. Liu, G. Yan, X., Lu, Z., et al., Chem. Mater., 2005, vol. 17, p. 4985.

    Article  CAS  Google Scholar 

  15. Hu, N.X., Esteghamatian, M., Xie, S., et al., Adv. Mater., 1999, vol. 11, no. 17, p. 1460.

    Article  CAS  Google Scholar 

  16. Wang, J.F., Jabbour, G.E., Mash, E.A., et al., Adv. Mater., 1999, vol. 11, no. 15, p. 1266.

    Article  CAS  Google Scholar 

  17. Feng, L., Wang, X., and Chena, Zh., Spectrochim. Acta, Part A, 2008, vol. 11, p. 312.

    Article  Google Scholar 

  18. Tang, H., Zhang, Zh., Yuan, J., et al., Synth. Met., 2009, vol. 159, p. 72.

    Article  CAS  Google Scholar 

  19. Doroshenko, A.O., Posokhov, E.A., Verezubova, A.A., and Ptyagina, L.M., J. Phys. Org. Chem., 2000, vol. 13, no. 5, p. 253.

    Article  CAS  Google Scholar 

  20. Mikhailov, I.E., Popov, L.D., Vikrishchuk, N.E., et al., Russ. J. Gen. Chem., 2015, vol. 85, no. 1, p. 203.

    Article  CAS  Google Scholar 

  21. Brammer, L., Bargard, M.D., Rodger, C.S., et al., Chem. Commun., 2001, p. 2468.

    Google Scholar 

  22. Kokunov, Yu.V., Gorbunova, Yu.E., and Kovalev, V.V., Russ. J. Inorg. Chem., 2008, vol. 53, no. 12, p. 1885.

    Article  Google Scholar 

  23. Che, C.-M., Tse, M.-C., Chan, C.W., et al., J. Am. Chem. Soc., 2000, vol. 122, p. 2464.

    Article  CAS  Google Scholar 

  24. Sun, D., Cao, R., Weng, J., et al., Dalton Trans., 2002, p. 291.

    Google Scholar 

  25. Chen, C.-Y., Zeng, J.Y., and Lee, H.M., Inorg. Chim. Acta, 2007, vol. 360, p. 21.

    Article  CAS  Google Scholar 

  26. Zheng, X.-F. and Zhu, L.-G., CrystEngComm, 2010, vol. 12, p. 2878.

    Article  CAS  Google Scholar 

  27. Tong, M.-L., Shi, J.-X., and Chen, X.-M., New J. Chem., 2002, vol. 26, p. 814.

    Article  CAS  Google Scholar 

  28. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.

    Article  CAS  Google Scholar 

  29. Xie, L.-X., Wei, M.-L., Duan, C.-Y., et al., Inorg. Chim. Acta, 2007, vol. 360, p. 2541.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    Yu. V. Kokunov, Yu. E. Gorbunova, V. V. Kovalev, G. A. Razgonyaeva & S. A. Kozyukhin

  2. Southern Federal University, Rostov-on-Don, 344104, Russia

    L. D. Popov & S. A. Borodkin

Authors
  1. Yu. V. Kokunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. E. Gorbunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. D. Popov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. V. Kovalev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. A. Razgonyaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. A. Kozyukhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. S. A. Borodkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Yu. V. Kokunov or L. D. Popov.

Additional information

Original Russian Text © Yu.V. Kokunov, Yu.E. Gorbunova, L.D. Popov, V.V. Kovalev, G.A. Razgonyaeva, S.A. Kozyukhin, S.A. Borodkin, 2016, published in Koordinatsionnaya Khimiya, 2016, Vol. 42, No. 6, pp. 323–328.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kokunov, Y.V., Gorbunova, Y.E., Popov, L.D. et al. Coordination silver polymer with the bridging anion of oxadiazolylacrylic acid: Synthesis, crystal structure, and luminescence properties. Russ J Coord Chem 42, 361–366 (2016). https://doi.org/10.1134/S1070328416060038

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328416060038

Search

Navigation