Skip to main content
SpringerLink
Log in

Two 3D zinc-bpe frameworks constructed from 2-carboxyl/sulfo-terephthalate: Crystal structures and luminescent properties

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Two new zinc(II) complexes with the formulas of [Zn(HTma)(Bpe)] (I) and [Zn1.5(Stp) (Bpe)(H2O)2] (II), where H3Tma = 1,2,4-trimellitic acid, Bpe = 1,2-bis(4-pyridyl)ethane, NaH2Stp = monosodium 2-sulfoterephthalate, have been prepared under hydrothermal conditions. Structural syntheses show complex I is a five-fold interpenetrated three-dimensional structure based on the diamond-like networks, however, complex II is a Bpe-pillared three-dimensional framework (CIF files CCDC nos. 1404475 (I) and 140447 (II)). Thermоgravimetric analyses show that complex I possesses high thermal stability up to 325°C and the dehydrated product of complex II also begins to decompose from 357°C. The luminescent properties of the two complexes are investigated in solid state.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Jena, H.S., Adhikary, A., and Konar, S., Inorg. Chem., 2014, vol. 53, p. 3926.

    Article  Google Scholar 

  2. Ren, Y.X., Zheng, X.J., Li, L.C., et al., Inorg. Chem., 2014, vol. 53, p. 12234.

    Article  CAS  Google Scholar 

  3. Qian, Yan-Tao, Peng, Ye-Dong, and Zhang, Wen-Wei, Chin. J. Inorg. Chem., 2015, vol. 31, no. 5, p. 857.

    CAS  Google Scholar 

  4. Zeng, M.H., Tan, Y.X., He, Y.P., et al., Inorg. Chem., 2013, vol. 52, p. 2353.

    Article  CAS  Google Scholar 

  5. Li, D.S., Wu, Y.P., Zhao, J., et al., Coord. Chem. Rev., 2014, vol. 261, p. 1.

    Article  CAS  Google Scholar 

  6. Sang, R.L. and Xu, L., Chem. Commun., 2013, vol. 49, p. 8344.

    Article  CAS  Google Scholar 

  7. Ren, Y.X., Ma, H.Y., Fu, F., et al., J. Inorg. Organomet. Polym., 2013, vol. 23, p. 646.

    Article  CAS  Google Scholar 

  8. Li, S.M., Zheng, X.J., Yuan, D.Q., et al., Inorg. Chem., 2012, vol. 51, p. 120.

    Google Scholar 

  9. Wei, N., Zhang, M.Y., Zhang, X.N., et al., Cryst. Growth Des., 2014, vol. 14, p. 3002.

    Article  CAS  Google Scholar 

  10. Maret, W.G. and Li, Y., Chem. Rev., 2009, vol. 109, no. 10, p. 4682.

    Article  CAS  Google Scholar 

  11. Fei, H.H., Han, C.S., Robins, J.C., and Oliver, S.R.J., Chem. Mater., 2013, vol. 25, no. 5, p. 647.

    Article  CAS  Google Scholar 

  12. He, Y.P., Tan, Y.X., and Zhang, J., Cryst. Growth Des., 2013, vol. 13, no. 1, p. 6.

    Article  CAS  Google Scholar 

  13. Li, H., Eddaoudi, M., O’Keeffe, M., and Yaghi, O.M., Nature, 1999, vol. 402, p. 276.

    Article  CAS  Google Scholar 

  14. Li, Y.W., Ma, H., Chen, Y.Q., et al., Cryst. Growth Des., 2012, vol. 12, no. 1, p. 189.

    Article  Google Scholar 

  15. Guo, Z.G., Cao, R., Wang, X., et al., J. Am. Chem. Soc., 2009, vol. 131, no. 20, p. 6894.

    Article  CAS  Google Scholar 

  16. Ren, Y.X., Xiao, S.S., Zheng, X.J., et al., Dalton Trans., 2012, vol. 41, p. 2639.

    Article  CAS  Google Scholar 

  17. Sheldrick, G.M., SADABS, Program for Empirical Absorption Correction of Area Detector Data, Göttingen Univ. of Göttingen, 1996.

  18. Sheldrick, G.M., SHELXL-97 and SHELXTL, Software Reference Manual, Version 5. 1, Madison Bruker AXS Inc., 1997.

    Google Scholar 

  19. SAINT, Area Detector Control and Integration Software, Madison (WI, USA)Siemens Analytiacl X-ray Instruments Inc., 1996.

  20. Ren, Yi-Xia, Tang, Long, Wu, Yu-Fei, et al., Chin. J. Inorg. Chem., 2012, vol. 28, no. 8, p. 1729.

    CAS  Google Scholar 

  21. Allendorf, M.D., Bauer, C.A., Bhakta, R.K., and Houk, R.J.T., Chem. Soc. Rev., 2009, vol. 38, p. 1330.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, School of Science, Xi’an Jiao Tong University, Xi’an, 710049, P.R. China

    Y. Ren & M. An

  2. College of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an, Shaanxi, 716000, P.R. China

    Y. Ren, H. Chai, M. An, L. Gao & G. Zhou

Authors
  1. Y. Ren
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Chai
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. An
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. Gao
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Y. Ren.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ren, Y., Chai, H., An, M. et al. Two 3D zinc-bpe frameworks constructed from 2-carboxyl/sulfo-terephthalate: Crystal structures and luminescent properties. Russ J Coord Chem 42, 338–344 (2016). https://doi.org/10.1134/S1070328416050067

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328416050067

Keywords

Search

Navigation