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Heterovalent Gold(I,III) complex ([Au{S2CN(CH2)6}2]3[AuCl2]2Cl]) n : Synthesis, structure, and 13C MAS NMR

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Abstract

The reaction of the freshly precipitated oxovanadium(IV) cyclo-hexamethylenedithiocarbamate complex with [AuCl4]– anions in a 2 M HCl solution is studied. The water-soluble heterovalent complex ([Au{S2CN(CH2)6}2]3[AuCl2]2Cl]) n (I) is formed due to the redox reaction. According to the X-ray diffraction data, structure I contains two species of complex cations [Au{S2CN(CH2)6}2]+ as conformers performing different structural functions: non-centrosymmetric cations and centrosymmetric cation B in a ratio of 2: 1. Cations A form centrosymmetric dimers [Au{2S2CN(CH2)6}4]2+ due to pairs of symmetrical secondary bonds Au…S. The aurophilic Au…Au and secondary Au…S interactions that occur between the complex cations and anions in crystal result in the formation of a polymer network.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    I. A. Lutsenko, M. A. Kiskin & G. G. Aleksandrov

  2. Institute of Geology and Nature Management, Far East Branch, Russian Academy of Sciences, Relochnyi per. 1, Blagoveshchensk, 675000, Russia

    A. V. Ivanov

Authors
  1. I. A. Lutsenko
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  2. A. V. Ivanov
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  3. M. A. Kiskin
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  4. G. G. Aleksandrov
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Correspondence to I. A. Lutsenko.

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Original Russian Text © I.A. Lutsenko, A.V. Ivanov, M.A. Kiskin, G.G. Aleksandrov, 2016, published in Koordinatsionnaya Khimiya, 2016, Vol. 42, No. 5, pp. 290–295.

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Lutsenko, I.A., Ivanov, A.V., Kiskin, M.A. et al. Heterovalent Gold(I,III) complex ([Au{S2CN(CH2)6}2]3[AuCl2]2Cl]) n : Synthesis, structure, and 13C MAS NMR. Russ J Coord Chem 42, 324–329 (2016). https://doi.org/10.1134/S1070328416040047

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  • DOI: https://doi.org/10.1134/S1070328416040047

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