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Binuclear metallochelates of 2-(N-tosylamino)benzal-2’-(hydroxymethyl)aniline: Syntheses, structures, and magnetic properties

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Abstract

Binuclear complexes of Co(II), Сu(II), and Pd(II) with 2-(N-tosylamino)benzal-2’-(hydroxymethyl)aniline are synthesized. The compositions and structures of the ligand and complexes are determined from the data of elemental analysis, IR spectroscopy, 1Н, 13С, and 15N NMR spectroscopy, X-ray absorption spectroscopy, and magnetochemical measurements in a temperature range of 294–77.4 K. All complexes are dimeric. The Cu…Cu and Cо…Cо distances equal to 3.03 and 2.99 Å, respectively, are obtained for the Cu(II) and Co(II) complexes. These complexes are characterized by the antiferromagnetic exchange interaction with 2J = –630 and –42 cm–1, respectively.

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia

    A. S. Burlov, Yu. V. Koshchienko, I. V. Pankov, G. S. Borodkin, T. A. Mazepina & A. I. Uraev

  2. Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russia

    V. G. Vlasenko

  3. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    S. I. Levchenkov & D. A. Garnovskii

  4. Kurchatov Institute Russian Research Center, pl. Kurchatova 1, Moscow, 123182, Russia

    Ya. V. Zubavichus & A. L. Trigub

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  1. A. S. Burlov
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  2. V. G. Vlasenko
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  3. Yu. V. Koshchienko
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  4. S. I. Levchenkov
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  10. D. A. Garnovskii
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Correspondence to A. S. Burlov.

Additional information

Original Russian Text © A.S. Burlov, V.G. Vlasenko, Yu.V. Koshchienko, S.I. Levchenkov, I.V. Pankov, Ya.V. Zubavichus, A.L. Trigub, G.S. Borodkin, T.A. Mazepina, D.A. Garnovskii, A.I. Uraev, 2016, published in Koordinatsionnaya Khimiya, 2016, Vol. 42, No. 4, pp. 237–244.

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Burlov, A.S., Vlasenko, V.G., Koshchienko, Y.V. et al. Binuclear metallochelates of 2-(N-tosylamino)benzal-2’-(hydroxymethyl)aniline: Syntheses, structures, and magnetic properties. Russ J Coord Chem 42, 267–273 (2016). https://doi.org/10.1134/S1070328416030027

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  • DOI: https://doi.org/10.1134/S1070328416030027

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