Russian Journal of Coordination Chemistry

, Volume 42, Issue 4, pp 267–273

Binuclear metallochelates of 2-(N-tosylamino)benzal-2’-(hydroxymethyl)aniline: Syntheses, structures, and magnetic properties

  • A. S. Burlov
  • V. G. Vlasenko
  • Yu. V. Koshchienko
  • S. I. Levchenkov
  • I. V. Pankov
  • Ya. V. Zubavichus
  • A. L. Trigub
  • G. S. Borodkin
  • T. A. Mazepina
  • D. A. Garnovskii
  • A. I. Uraev
Article

DOI: 10.1134/S1070328416030027

Cite this article as:
Burlov, A.S., Vlasenko, V.G., Koshchienko, Y.V. et al. Russ J Coord Chem (2016) 42: 267. doi:10.1134/S1070328416030027

Abstract

Binuclear complexes of Co(II), Сu(II), and Pd(II) with 2-(N-tosylamino)benzal-2’-(hydroxymethyl)aniline are synthesized. The compositions and structures of the ligand and complexes are determined from the data of elemental analysis, IR spectroscopy, 1Н, 13С, and 15N NMR spectroscopy, X-ray absorption spectroscopy, and magnetochemical measurements in a temperature range of 294–77.4 K. All complexes are dimeric. The Cu…Cu and Cо…Cо distances equal to 3.03 and 2.99 Å, respectively, are obtained for the Cu(II) and Co(II) complexes. These complexes are characterized by the antiferromagnetic exchange interaction with 2J = –630 and –42 cm–1, respectively.

Copyright information

© Pleiades Publishing, Ltd. 2016

Authors and Affiliations

  • A. S. Burlov
    • 1
  • V. G. Vlasenko
    • 2
  • Yu. V. Koshchienko
    • 1
  • S. I. Levchenkov
    • 3
  • I. V. Pankov
    • 1
  • Ya. V. Zubavichus
    • 4
  • A. L. Trigub
    • 4
  • G. S. Borodkin
    • 1
  • T. A. Mazepina
    • 1
  • D. A. Garnovskii
    • 3
  • A. I. Uraev
    • 1
  1. 1.Research Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-DonRussia
  2. 2.Research Institute of PhysicsSouthern Federal UniversityRostov-on-DonRussia
  3. 3.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  4. 4.Kurchatov Institute Russian Research CenterMoscowRussia

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