Russian Journal of Coordination Chemistry

, Volume 42, Issue 4, pp 267–273 | Cite as

Binuclear metallochelates of 2-(N-tosylamino)benzal-2’-(hydroxymethyl)aniline: Syntheses, structures, and magnetic properties

  • A. S. Burlov
  • V. G. Vlasenko
  • Yu. V. Koshchienko
  • S. I. Levchenkov
  • I. V. Pankov
  • Ya. V. Zubavichus
  • A. L. Trigub
  • G. S. Borodkin
  • T. A. Mazepina
  • D. A. Garnovskii
  • A. I. Uraev
Article

Abstract

Binuclear complexes of Co(II), Сu(II), and Pd(II) with 2-(N-tosylamino)benzal-2’-(hydroxymethyl)aniline are synthesized. The compositions and structures of the ligand and complexes are determined from the data of elemental analysis, IR spectroscopy, 1Н, 13С, and 15N NMR spectroscopy, X-ray absorption spectroscopy, and magnetochemical measurements in a temperature range of 294–77.4 K. All complexes are dimeric. The Cu…Cu and Cо…Cо distances equal to 3.03 and 2.99 Å, respectively, are obtained for the Cu(II) and Co(II) complexes. These complexes are characterized by the antiferromagnetic exchange interaction with 2J = –630 and –42 cm–1, respectively.

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References

  1. 1.
    Ovcharenko, V.I. and Sagdeev, R.Z., Russ. Chem. Rev., 1999, vol. 68, no. 5, p. 345.CrossRefGoogle Scholar
  2. 2.
    Kalinnikov, V.T., Rakitin, Yu.V., and Novotortsev, V.M., Russ. Chem. Rev., 2003, vol. 72, no. 12, p. 995.CrossRefGoogle Scholar
  3. 3.
    Magnetic Molecular Magnetism, Gatteshi D., Kahn O., Miller J.S., and Palacio F., Eds., Dordrecht Kluwer Acad., 1985.Google Scholar
  4. 4.
    Pestov, A.V., Slepukhin, P.A., and Charushin, V.N., Russ. Chem. Rev., 2015, vol. 84, no. 3, p. 310.CrossRefGoogle Scholar
  5. 5.
    Magnetism: Molecules to Materials, Miller J.S. and Drillon, V., Eds., Berlin Verlag-Chem., 2002.Google Scholar
  6. 6.
    Chaudhury, P., Coord. Chem. Rev., 2003, vol. 243, no. 1, p. 143.CrossRefGoogle Scholar
  7. 7.
    Kahn, O., Galy, J., Journaux, Y., and Mongenstern-Badarau, I., Russ. J. Struct. Chem., 1982, vol. 104, no. 18, p. 2165.Google Scholar
  8. 8.
    Levchenkov, S.I., Shcherbakov, I.N., Popov, L.D., et al., Russ. J. Struct. Chem., 2015, vol. 56, no. 1, p. 113.CrossRefGoogle Scholar
  9. 9.
    Darensbourg, D.J., Mackiewicz, R.M., Phelps, A.L., and Billodeaux, D.R., Acc. Chem. Res., 2004, vol. 37, p. 836.CrossRefGoogle Scholar
  10. 10.
    Ivanchev, S.S., Russ. Chem. Rev., 2007, vol. 76, no. 7, p. 617.CrossRefGoogle Scholar
  11. 11.
    Metelitsa, A.V., Burlov, A.S., Bezuglyi, S.O., et al., Russ. J. Coord. Chem., 2006, vol. 32, no. 12, p. 858.CrossRefGoogle Scholar
  12. 12.
    Qiao, J., Wang, L.D., and Duan, L., Inorg. Chem., 2004, vol. 43, no. 16, p. 5096.CrossRefGoogle Scholar
  13. 13.
    Kogan, V.A., Zelentsov, V.V., Osipov, O.A., and Burlov, A.S., Russ. Chem. Rev., 1979, vol. 48, no. 7, p. 645.CrossRefGoogle Scholar
  14. 14.
    Kogan, V.A., Lukov, V.V., and Shcherbakov, I.N., Russ. J. Coord. Chem., 2010, vol. 36, no. 6, p. 401.CrossRefGoogle Scholar
  15. 15.
    Burlov, A.S., Antsyshkina, A.S., Romero, Kh., et al., Zh. Neorg. Khim., 1995, vol. 40, no. 9, p. 1480.Google Scholar
  16. 16.
    Garnovskii, A.D., Burlov, A.S., Lukov, V.V., et al., Russ. J. Coord. Chem., 1996, vol. 22, no. 11, p. 786.Google Scholar
  17. 17.
    Garnovskii, A.D., Burlov, A.S., Garnovskii, D.A., et al., Polyhedron, 1999, vol. 18, no. 6, p. 863.CrossRefGoogle Scholar
  18. 18.
    Antsyshkina, A.S., Sadikov, G.G., Burlov, A.S., et al., Russ. J. Coord. Chem., 2000, vol. 26, no. 10, p. 730.Google Scholar
  19. 19.
    Antsyshkina, A.S., Sadikov, G.G., Burlov, A.S., et al., Russ. J. Inorg. Chem., 2000, vol. 45, no. 11, p. 1666.Google Scholar
  20. 20.
    Garnovskii, D.A., Sadikov, G.G., Antsyshkina, A.S., et al., Cryst. Rep., 2003, vol. 48, no. 3, p. 426.CrossRefGoogle Scholar
  21. 21.
    Antsyshkina, A.S., Sadikov, G.G., Burlov, A.S., et al., Russ. J. Inorg. Chem., 2005, vol. 50, no. 3, p. 346.Google Scholar
  22. 22.
    Uraev, A.I., Vasilchenko, I.S., Ikorskii, V.N., et al., Mend. Commun., 2005, vol. 15, no. 4, p. 133.CrossRefGoogle Scholar
  23. 23.
    Burlov, A.S., Vlasenko, V.G., Garnovskii, D.A., et al., J. Struct. Chem., 2015, vol. 56, no. 3, p. 504.CrossRefGoogle Scholar
  24. 24.
    Burlov, A.S., Koshchienko, Yu.V., Ikorskii, V.N., et al., Russ. J. Inorg. Chem., 2006, vol. 51, no. 7, p. 1065.CrossRefGoogle Scholar
  25. 25.
    Burlov, A.S., Ikorskii, V.N., Uraev, A.I., et al., Russ. J. Gen. Chem., 2006, vol. 76, no. 8, p. 1282.CrossRefGoogle Scholar
  26. 26.
    Garnovskii, A.D., Ikorskii, V.N., Uraev, A.I., et al., J. Coord. Chem., 2007, vol. 60, no. 14, p. 1493.CrossRefGoogle Scholar
  27. 27.
    Burlov, A.S., Koshchienko, Yu.V., Lyssenko, K.A., et al., J. Coord. Chem., 2008, vol. 61, no. 1, p. 85.CrossRefGoogle Scholar
  28. 28.
    Burlov, A.S., Ikorskii, V.N., Nikolaevskii, S.A., et al., Russ. J. Inorg. Chem., 2008, vol. 53, no. 10, p. 1566.CrossRefGoogle Scholar
  29. 29.
    Burlov, A.S., Nikolaevskii, S.A., Bogomyakov, A.S., et al., Russ. J. Coord. Chem., 2009, vol. 35, no. 7, p. 486.CrossRefGoogle Scholar
  30. 30.
    Nikolaevskii, S.A., Burlov, A.S., Bogomyakov, A.S., et al., Russ. J. Gen. Chem., 2012, vol. 82, no. 11, p. 1770.CrossRefGoogle Scholar
  31. 31.
    Shmakova, T.O., Garnovskii, D.A., Lysenko, K.A., et al., Russ. J. Coord. Chem., 2009, vol. 35, no. 9, p. 657.CrossRefGoogle Scholar
  32. 32.
    Shmakova, T.O., Garnovskii, D.A., Lysenko, K.A., et al., Izv. Akad. Nauk, Ser. Khim., 2009, no. 7, p. 1344.Google Scholar
  33. 33.
    Borisova, A.O., Garnovskii, D.A., Korshunova, E.V., et al., Izv. Akad. Nauk, Ser. Khim., 2012, no. 11, p. 2053.Google Scholar
  34. 34.
    Burlov, A.S., Uraev, A.I., Ikorskii, V.N., et al., Russ. J. Gen. Chem., 2008, vol. 78, no. 6, p. 1230.CrossRefGoogle Scholar
  35. 35.
    Burlov, A.S., Uraev, A.I., Garnovskii, D.A., et al., J. Mol. Struct., 2014, vol. 1064, p. 111.CrossRefGoogle Scholar
  36. 36.
    Popov, L.D., Tupolova, Yu.P., Lukov, V.V., et al., Inorg. Chim. Acta, 2009, vol. 362, no. 6, p. 1673.CrossRefGoogle Scholar
  37. 37.
    Garnovskii, A.D., Vasil’chenko, I.S., Garnovskii, D.A., et al., Ross. Khim. Zh., 2009, vol. 53, no. 1, p. 100.Google Scholar
  38. 38.
    Garnovskii, A.D., Burlov, A.S., Vasil’chenko, I.S., et al., Russ. J. Coord. Chem., 2010, vol. 36, no. 2, p. 81.CrossRefGoogle Scholar
  39. 39.
    Chernova, N.I., Ryabokobylko, Yu.S., Brudz’, V.G., and Bolotin, B.M., Zh. Org. Khim., 1971, vol. 7, no. 8, p. 1680.Google Scholar
  40. 40.
    Chernyshov, A.A., Veligzhanin, A.A., and Zubavichus, Y.V., Nucl. Instr. Meth. Phys. Res. A, 2009, vol. 603, p. 95.CrossRefGoogle Scholar
  41. 41.
    Kochubei, D.I., Babanov, Yu.A., Zamaraev, L.I., et al., Rentgenospektral’nyi metod izucheniya struktury amorfnykh tel EXAFS-spektroskopiya (X-Ray Spectral Method for Solid Structure Investigation EXAFS Spectroscopy), Novosibirsk: Nauka SO, 1988.Google Scholar
  42. 42.
    Newville, M., J. Synchrotron Rad., 2001, no. 8, p. 96.CrossRefGoogle Scholar
  43. 43.
    Zabinski, S.I., Rehr, J.J., Ankudinov, A., and Alber, R.C., Phys. Rev. B: Condens. Matter Mater. Phys., 1995, vol. 52, p. 2995.CrossRefGoogle Scholar
  44. 44.
    Rakitin, Yu.V. and Kalinnikov, V.T., Sovremennaya magnetokhimiya (Modern Magnetochemistry), St. Petersburg Nauka, 1994.Google Scholar
  45. 45.
    Kahn, O., Molecular Magnetism, New York VCH Publishers, 1993.Google Scholar
  46. 46.
    Bleaney, B. and Bowers, K.D., Proc. R. Soc. London. A, 1952, vol. 214. no. 1119, p. 451.CrossRefGoogle Scholar
  47. 47.
    Uraev, A.I., Doctoral (Chem.) Dissertation, Rostov-on- Don Southern Federal Univ., 2014.Google Scholar
  48. 48.
    Garnovskii, D.A., Antsyshkina, A.S., Churakov, A.V., et al., Russ. J. Inorg. Chem., 2014, vol. 59, no. 5, p. 431.CrossRefGoogle Scholar
  49. 49.
    Funke, H. and Chukalina, M., FZR Annual Reports, 2001, vol. 343, p. 45.Google Scholar
  50. 50.
    Funke, H., Scheinhost, A.C., and Chukalina, M., Phys. Rev. B, 2005, vol. 71, p. 094110.CrossRefGoogle Scholar
  51. 51.
    Funke, H., Chukalina, M., and Scheinost, A.C., J. Synchrotron Rad. 2007, vol. 14, p. 426.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2016

Authors and Affiliations

  • A. S. Burlov
    • 1
  • V. G. Vlasenko
    • 2
  • Yu. V. Koshchienko
    • 1
  • S. I. Levchenkov
    • 3
  • I. V. Pankov
    • 1
  • Ya. V. Zubavichus
    • 4
  • A. L. Trigub
    • 4
  • G. S. Borodkin
    • 1
  • T. A. Mazepina
    • 1
  • D. A. Garnovskii
    • 3
  • A. I. Uraev
    • 1
  1. 1.Research Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-DonRussia
  2. 2.Research Institute of PhysicsSouthern Federal UniversityRostov-on-DonRussia
  3. 3.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  4. 4.Kurchatov Institute Russian Research CenterMoscowRussia

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