Abstract
The binuclear copper(II) complex based on azomethine, being a condensation product of 2-aminoethanol with 1-phenyl-1,2,3-butanetrione phenylhydrazone, is structurally characterized (CIF file CCDC 1059996). The structure is compared with the structure of an analog containing the axially coordinated pyridine molecule. The influence of the axial coordination of pyridine on the magnetic exchange interaction is studied by the DFT method in the broken symmetry approach.
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Original Russian Text © L.D. Popov, S.I. Levchenkov, I.N. Shcherbakov, V.V. Tkachev, G.V. Shilov, Yu.P. Tupolova, D.S. Samorodnyaya, E.V. Ivannikova, V.V. Lukov, V.A. Kogan, 2016, published in Koordinatsionnaya Khimiya, 2016, Vol. 42, No. 2, pp. 67–71.
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Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N. et al. Crystal structure and magnetic properties of binuclear copper(II) complex with 2-N-(phenylhydrazono)-3-((ethyl-2-olato)imino)-1-phenyl-1,2,3-butanetrione. Russ J Coord Chem 42, 81–84 (2016). https://doi.org/10.1134/S1070328416010024
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DOI: https://doi.org/10.1134/S1070328416010024